Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide

In this article, we present an overview on the thermocatalytic reaction of hydrogen peroxide (H 2 O 2 ) gas on a manganese (IV) oxide (MnO 2 ) catalytic structure. The principle of operation and manufacturing techniques are introduced for a calorimetric H 2 O 2 gas...

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Bibliographic Details
Main Authors: Zaid B. Jildeh, Jan Oberländer, Patrick Kirchner, Patrick H. Wagner, Michael J. Schöning
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/8/4/262
Description
Summary:In this article, we present an overview on the thermocatalytic reaction of hydrogen peroxide (H 2 O 2 ) gas on a manganese (IV) oxide (MnO 2 ) catalytic structure. The principle of operation and manufacturing techniques are introduced for a calorimetric H 2 O 2 gas sensor based on porous MnO 2 . Results from surface analyses by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) of the catalytic material provide indication of the H 2 O 2 dissociation reaction schemes. The correlation between theory and the experiments is documented in numerical models of the catalytic reaction. The aim of the numerical models is to provide further information on the reaction kinetics and performance enhancement of the porous MnO 2 catalyst.
ISSN:2079-4991