Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide

In this article, we present an overview on the thermocatalytic reaction of hydrogen peroxide (H 2 O 2 ) gas on a manganese (IV) oxide (MnO 2 ) catalytic structure. The principle of operation and manufacturing techniques are introduced for a calorimetric H 2 O 2 gas...

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Main Authors: Zaid B. Jildeh, Jan Oberländer, Patrick Kirchner, Patrick H. Wagner, Michael J. Schöning
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/8/4/262
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author Zaid B. Jildeh
Jan Oberländer
Patrick Kirchner
Patrick H. Wagner
Michael J. Schöning
author_facet Zaid B. Jildeh
Jan Oberländer
Patrick Kirchner
Patrick H. Wagner
Michael J. Schöning
author_sort Zaid B. Jildeh
collection DOAJ
description In this article, we present an overview on the thermocatalytic reaction of hydrogen peroxide (H 2 O 2 ) gas on a manganese (IV) oxide (MnO 2 ) catalytic structure. The principle of operation and manufacturing techniques are introduced for a calorimetric H 2 O 2 gas sensor based on porous MnO 2 . Results from surface analyses by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) of the catalytic material provide indication of the H 2 O 2 dissociation reaction schemes. The correlation between theory and the experiments is documented in numerical models of the catalytic reaction. The aim of the numerical models is to provide further information on the reaction kinetics and performance enhancement of the porous MnO 2 catalyst.
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spelling doaj.art-51e59f44f7134030a30b2153ca8353432022-12-21T17:58:03ZengMDPI AGNanomaterials2079-49912018-04-018426210.3390/nano8040262nano8040262Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen PeroxideZaid B. Jildeh0Jan Oberländer1Patrick Kirchner2Patrick H. Wagner3Michael J. Schöning4Imagine Engineering GmbH, Kopernikusstr. 13b, 50126 Bergheim, GermanyInstitute of Nano- and Biotechnologies (INB), Aachen University of Applied Sciences, Heinrich-Mussmann-Str. 1, 52428 Jülich, GermanyImagine Engineering GmbH, Kopernikusstr. 13b, 50126 Bergheim, GermanySoft-Matter Physics and Biophysics Section, KU Leuven, Celestijnenlaan 200 D, 3001 Leuven, BelgiumInstitute of Nano- and Biotechnologies (INB), Aachen University of Applied Sciences, Heinrich-Mussmann-Str. 1, 52428 Jülich, GermanyIn this article, we present an overview on the thermocatalytic reaction of hydrogen peroxide (H 2 O 2 ) gas on a manganese (IV) oxide (MnO 2 ) catalytic structure. The principle of operation and manufacturing techniques are introduced for a calorimetric H 2 O 2 gas sensor based on porous MnO 2 . Results from surface analyses by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) of the catalytic material provide indication of the H 2 O 2 dissociation reaction schemes. The correlation between theory and the experiments is documented in numerical models of the catalytic reaction. The aim of the numerical models is to provide further information on the reaction kinetics and performance enhancement of the porous MnO 2 catalyst.http://www.mdpi.com/2079-4991/8/4/262hydrogen peroxidemanganese (IV) oxidecatalytic decompositioncalorimetric gas sensornumerical simulation
spellingShingle Zaid B. Jildeh
Jan Oberländer
Patrick Kirchner
Patrick H. Wagner
Michael J. Schöning
Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
Nanomaterials
hydrogen peroxide
manganese (IV) oxide
catalytic decomposition
calorimetric gas sensor
numerical simulation
title Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
title_full Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
title_fullStr Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
title_full_unstemmed Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
title_short Thermocatalytic Behavior of Manganese (IV) Oxide as Nanoporous Material on the Dissociation of a Gas Mixture Containing Hydrogen Peroxide
title_sort thermocatalytic behavior of manganese iv oxide as nanoporous material on the dissociation of a gas mixture containing hydrogen peroxide
topic hydrogen peroxide
manganese (IV) oxide
catalytic decomposition
calorimetric gas sensor
numerical simulation
url http://www.mdpi.com/2079-4991/8/4/262
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