A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode

Cathode materials with mixed ion-electron conductivity (MIEC) are necessary for the development of low or intermediate temperature solid oxide fuel cells. Perovskite and perovskite-related materials are promising candidates on this role. In the review the conductivity and the thermal expansion of ma...

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Main Authors: A. V. Nikonov, K. A. Kuterbekov, K. Zh. Bekmyrza, N. B. Pavzderin
Format: Article
Language:English
Published: L.N. Gumilyov Eurasian National University 2021-11-01
Series:Eurasian Journal of Physics and Functional Materials
Subjects:
Online Access:https://www.ephys.kz/jour/article/view/95
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author A. V. Nikonov
K. A. Kuterbekov
K. Zh. Bekmyrza
N. B. Pavzderin
author_facet A. V. Nikonov
K. A. Kuterbekov
K. Zh. Bekmyrza
N. B. Pavzderin
author_sort A. V. Nikonov
collection DOAJ
description Cathode materials with mixed ion-electron conductivity (MIEC) are necessary for the development of low or intermediate temperature solid oxide fuel cells. Perovskite and perovskite-related materials are promising candidates on this role. In the review the conductivity and the thermal expansion of materials with various types of perovskite-related structures such as pure perovskite, double perovskite, brownmillerite and Ruddlesden-Popper phases have been compared. And the literature data on the values of the electronic and ionic conductivities, the oxygen diffusion coefficient, and the thermal expansion coefficient of various compositions have been collected. It was shown that the disordered cubic perovskites possess the higher electronic conductivity whereas the layered perovskites and materials with the Ruddlesden-Popper structure have higher ionic conductivity and lower value of thermal expansion.
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spelling doaj.art-51e7d0c6cf184d79aa48c91e1ce7f4cb2022-12-21T23:33:18ZengL.N. Gumilyov Eurasian National UniversityEurasian Journal of Physics and Functional Materials2522-98692616-85372021-11-012327429210.29317/ejpfm.201802030994A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathodeA. V. Nikonov0K. A. Kuterbekov1K. Zh. Bekmyrza2N. B. Pavzderin3Institute of Electrophysics Ural Branch Russian Academy of SciencesL.N. Gumilyov Eurasian National UniversityL.N. Gumilyov Eurasian National UniversityInstitute of Electrophysics Ural Branch Russian Academy of SciencesCathode materials with mixed ion-electron conductivity (MIEC) are necessary for the development of low or intermediate temperature solid oxide fuel cells. Perovskite and perovskite-related materials are promising candidates on this role. In the review the conductivity and the thermal expansion of materials with various types of perovskite-related structures such as pure perovskite, double perovskite, brownmillerite and Ruddlesden-Popper phases have been compared. And the literature data on the values of the electronic and ionic conductivities, the oxygen diffusion coefficient, and the thermal expansion coefficient of various compositions have been collected. It was shown that the disordered cubic perovskites possess the higher electronic conductivity whereas the layered perovskites and materials with the Ruddlesden-Popper structure have higher ionic conductivity and lower value of thermal expansion.https://www.ephys.kz/jour/article/view/95cathodeperovskite-related structureelectronic and ionic conductivitythermal expensionsofc
spellingShingle A. V. Nikonov
K. A. Kuterbekov
K. Zh. Bekmyrza
N. B. Pavzderin
A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
Eurasian Journal of Physics and Functional Materials
cathode
perovskite-related structure
electronic and ionic conductivity
thermal expension
sofc
title A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
title_full A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
title_fullStr A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
title_full_unstemmed A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
title_short A brief review of conductivity and thermal expansion of perovskite-related oxides for SOFC cathode
title_sort brief review of conductivity and thermal expansion of perovskite related oxides for sofc cathode
topic cathode
perovskite-related structure
electronic and ionic conductivity
thermal expension
sofc
url https://www.ephys.kz/jour/article/view/95
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