Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives
This study presents a novel method for synthesizing 1,4-disubstituted 1,2,3-triazole derivatives through a one-pot, multi-component addition reaction using flower-like Cu2O microbeads as a catalyst. The flower-like Cu2O microbeads were synthesized using an aqueous extract of Artimisia Campestris L....
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2024-01-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2023.1342988/full |
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| author | Halla Abdelbaki Halla Abdelbaki Amar Djemoui Lahcene Souli Ahmed Souadia Mohammed Ridha Ouahrani Mohammed Ridha Ouahrani Brahim Djemoui Mokhtar Boualem Lahrech Mohammed Messaoudi Ilham Ben Amor Adel Benarfa Adel Benarfa Ali Alsalme Mikhael Bechelany Mikhael Bechelany Ahmed Barhoum |
| author_facet | Halla Abdelbaki Halla Abdelbaki Amar Djemoui Lahcene Souli Ahmed Souadia Mohammed Ridha Ouahrani Mohammed Ridha Ouahrani Brahim Djemoui Mokhtar Boualem Lahrech Mohammed Messaoudi Ilham Ben Amor Adel Benarfa Adel Benarfa Ali Alsalme Mikhael Bechelany Mikhael Bechelany Ahmed Barhoum |
| author_sort | Halla Abdelbaki |
| collection | DOAJ |
| description | This study presents a novel method for synthesizing 1,4-disubstituted 1,2,3-triazole derivatives through a one-pot, multi-component addition reaction using flower-like Cu2O microbeads as a catalyst. The flower-like Cu2O microbeads were synthesized using an aqueous extract of Artimisia Campestris L. This extract demonstrated the capability to reduce and stabilize Cu2O particles during their initial formation, resulting in the formation of a porous flower-like morphology. These Cu2O microbeads exhibit distinctive features, including a cubic close-packed (ccp) crystal structure with an average crystallite size of 22.8 nm, bandgap energy of 2.7 eV and a particle size of 6 µm. Their catalytic activity in synthesizing 1,4-disubstituted 1,2,3-triazole derivatives was investigated through systematic exploration of key parameters such as catalyst quantity (1, 5, 10, 15, 20, and 30 mg/mL), solvent type (dimethylformamide/H2O, ethanol/H2O, dichloromethane/H2O, chloroform, acetone, and dimethyl sulfoxide), and catalyst reusability (four cycles). The Cu2O microbeads significantly increased the product yield from 20% to 85.3%. The green synthesis and outstanding catalytic attributes make these flower-like Cu2O microbeads promising, efficient, and recyclable catalysts for sustainable and effective chemical transformations. |
| first_indexed | 2024-03-08T13:31:28Z |
| format | Article |
| id | doaj.art-51eb7e1aaced4ac5aac88238db3327fd |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-03-08T13:31:28Z |
| publishDate | 2024-01-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-51eb7e1aaced4ac5aac88238db3327fd2024-01-17T08:45:44ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462024-01-011110.3389/fchem.2023.13429881342988Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivativesHalla Abdelbaki0Halla Abdelbaki1Amar Djemoui2Lahcene Souli3Ahmed Souadia4Mohammed Ridha Ouahrani5Mohammed Ridha Ouahrani6Brahim Djemoui7Mokhtar Boualem Lahrech8Mohammed Messaoudi9Ilham Ben Amor10Adel Benarfa11Adel Benarfa12Ali Alsalme13Mikhael Bechelany14Mikhael Bechelany15Ahmed Barhoum16Department of Chemistry, Faculty of Exact Sciences, University of El Oued, El Oued, AlgeriaLaboratory of Biodiversity and Application of Biotechnology in the Agricultural Field, Faculty of Natural Sciences and Life, University of El Oued, El Oued, AlgeriaLaboratory of Organic Chemistry and Natural Substance, Department of Chemistry, Faculty of Exact Sciences and Computer Science, ZIANE Achour University, Djelfa, AlgeriaLaboratory of Organic Chemistry and Natural Substance, Department of Chemistry, Faculty of Exact Sciences and Computer Science, ZIANE Achour University, Djelfa, AlgeriaLaboratory of Physico-Chemistry of Materials and Environment, Department of Chemistry, Faculty of Exact Sciences and Computer Science, ZIANE Achour University, Djelfa, AlgeriaDepartment of Chemistry, Faculty of Exact Sciences, University of El Oued, El Oued, AlgeriaLaboratory of Biodiversity and Application of Biotechnology in the Agricultural Field, Faculty of Natural Sciences and Life, University of El Oued, El Oued, AlgeriaDepartment of Chemistry, Faculty of Exact and Applied Sciences (FSEA), Oran University1, Oran, AlgeriaLaboratory of Organic Chemistry and Natural Substance, Department of Chemistry, Faculty of Exact Sciences and Computer Science, ZIANE Achour University, Djelfa, AlgeriaNuclear Research Centre of Birine (CRNB), Djelfa, AlgeriaDepartment of Process Engineering and Petrochemical, Faculty of Technology, University of El Oued, El Oued, AlgeriaLaboratoire des Sciences Fondamentales (LSF), University of Amar Télidji Laghouat, Laghouat, AlgeriaCentre de Recherche Scientifique et Technique en Analyses Physico-Chimiques (CRAPC)-PTAPC, Laghouat, Algeria0Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia1InstitutEuropéen des Membranes (IEM), UMR 5635, University Montpellier, ENSCM, CNRS, Place Eugène Bataillon, Montpellier, France2Gulf University for Science and Technology, GUST, Mubarak Al-Abdullah, Kuwait3NanoStruc Research Group, Chemistry Department, Faculty of Science, Helwan University, Cairo, EgyptThis study presents a novel method for synthesizing 1,4-disubstituted 1,2,3-triazole derivatives through a one-pot, multi-component addition reaction using flower-like Cu2O microbeads as a catalyst. The flower-like Cu2O microbeads were synthesized using an aqueous extract of Artimisia Campestris L. This extract demonstrated the capability to reduce and stabilize Cu2O particles during their initial formation, resulting in the formation of a porous flower-like morphology. These Cu2O microbeads exhibit distinctive features, including a cubic close-packed (ccp) crystal structure with an average crystallite size of 22.8 nm, bandgap energy of 2.7 eV and a particle size of 6 µm. Their catalytic activity in synthesizing 1,4-disubstituted 1,2,3-triazole derivatives was investigated through systematic exploration of key parameters such as catalyst quantity (1, 5, 10, 15, 20, and 30 mg/mL), solvent type (dimethylformamide/H2O, ethanol/H2O, dichloromethane/H2O, chloroform, acetone, and dimethyl sulfoxide), and catalyst reusability (four cycles). The Cu2O microbeads significantly increased the product yield from 20% to 85.3%. The green synthesis and outstanding catalytic attributes make these flower-like Cu2O microbeads promising, efficient, and recyclable catalysts for sustainable and effective chemical transformations.https://www.frontiersin.org/articles/10.3389/fchem.2023.1342988/fullcuprous oxideflower-like nanostructuresArtimisia Campestris L. extractgreen synthesis1,4-disubstituted 1,2,3-triazoles |
| spellingShingle | Halla Abdelbaki Halla Abdelbaki Amar Djemoui Lahcene Souli Ahmed Souadia Mohammed Ridha Ouahrani Mohammed Ridha Ouahrani Brahim Djemoui Mokhtar Boualem Lahrech Mohammed Messaoudi Ilham Ben Amor Adel Benarfa Adel Benarfa Ali Alsalme Mikhael Bechelany Mikhael Bechelany Ahmed Barhoum Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives Frontiers in Chemistry cuprous oxide flower-like nanostructures Artimisia Campestris L. extract green synthesis 1,4-disubstituted 1,2,3-triazoles |
| title | Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives |
| title_full | Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives |
| title_fullStr | Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives |
| title_full_unstemmed | Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives |
| title_short | Plant mediated synthesis of flower-like Cu2O microbeads from Artimisia campestris L. extract for the catalyzed synthesis of 1,4-disubstituted 1,2,3-triazole derivatives |
| title_sort | plant mediated synthesis of flower like cu2o microbeads from artimisia campestris l extract for the catalyzed synthesis of 1 4 disubstituted 1 2 3 triazole derivatives |
| topic | cuprous oxide flower-like nanostructures Artimisia Campestris L. extract green synthesis 1,4-disubstituted 1,2,3-triazoles |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2023.1342988/full |
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