Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
Ceramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The mor...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-07-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/12/7/1523 |
_version_ | 1797562922611769344 |
---|---|
author | Dong Zhao Wei Liu Yucai Shen Guodong Jiang Tingwei Wang |
author_facet | Dong Zhao Wei Liu Yucai Shen Guodong Jiang Tingwei Wang |
author_sort | Dong Zhao |
collection | DOAJ |
description | Ceramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The morphology of AF in the composites system was observed by optical microscopy (OM) and scanning electron microscope (SEM). The effects of the observed AF network structures on the solvent resistance, mechanical properties, ablative resistance, self-supporting property, and ceramifiable properties of the composites were investigated. Results suggested that the existence of the AF network structure improved the vulcanization properties, solvent resistance, thermal stability, and ablative resistance of the EPDM composites. An excellent self-supporting property of the EPDM composites was obtained by combining the formation of the AF network and the formation of crystalline phases at higher temperature (above 600 °C). The thermal shrinkage performance of AF and the increased thermal stability of the EPDM composites improved the ceramifiable properties of the EPDM composites. |
first_indexed | 2024-03-10T18:35:29Z |
format | Article |
id | doaj.art-51fee5ae688742c3a142219f691d4a55 |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-10T18:35:29Z |
publishDate | 2020-07-01 |
publisher | MDPI AG |
record_format | Article |
series | Polymers |
spelling | doaj.art-51fee5ae688742c3a142219f691d4a552023-11-20T06:18:08ZengMDPI AGPolymers2073-43602020-07-01127152310.3390/polym12071523Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid FiberDong Zhao0Wei Liu1Yucai Shen2Guodong Jiang3Tingwei Wang4College of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCeramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The morphology of AF in the composites system was observed by optical microscopy (OM) and scanning electron microscope (SEM). The effects of the observed AF network structures on the solvent resistance, mechanical properties, ablative resistance, self-supporting property, and ceramifiable properties of the composites were investigated. Results suggested that the existence of the AF network structure improved the vulcanization properties, solvent resistance, thermal stability, and ablative resistance of the EPDM composites. An excellent self-supporting property of the EPDM composites was obtained by combining the formation of the AF network and the formation of crystalline phases at higher temperature (above 600 °C). The thermal shrinkage performance of AF and the increased thermal stability of the EPDM composites improved the ceramifiable properties of the EPDM composites.https://www.mdpi.com/2073-4360/12/7/1523EPDMceramifiablearamid fiberself-supportingthermal stability |
spellingShingle | Dong Zhao Wei Liu Yucai Shen Guodong Jiang Tingwei Wang Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber Polymers EPDM ceramifiable aramid fiber self-supporting thermal stability |
title | Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber |
title_full | Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber |
title_fullStr | Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber |
title_full_unstemmed | Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber |
title_short | Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber |
title_sort | improved self supporting and ceramifiable properties of ceramifiable epdm composites by adding aramid fiber |
topic | EPDM ceramifiable aramid fiber self-supporting thermal stability |
url | https://www.mdpi.com/2073-4360/12/7/1523 |
work_keys_str_mv | AT dongzhao improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber AT weiliu improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber AT yucaishen improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber AT guodongjiang improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber AT tingweiwang improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber |