Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber

Ceramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The mor...

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Main Authors: Dong Zhao, Wei Liu, Yucai Shen, Guodong Jiang, Tingwei Wang
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/7/1523
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author Dong Zhao
Wei Liu
Yucai Shen
Guodong Jiang
Tingwei Wang
author_facet Dong Zhao
Wei Liu
Yucai Shen
Guodong Jiang
Tingwei Wang
author_sort Dong Zhao
collection DOAJ
description Ceramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The morphology of AF in the composites system was observed by optical microscopy (OM) and scanning electron microscope (SEM). The effects of the observed AF network structures on the solvent resistance, mechanical properties, ablative resistance, self-supporting property, and ceramifiable properties of the composites were investigated. Results suggested that the existence of the AF network structure improved the vulcanization properties, solvent resistance, thermal stability, and ablative resistance of the EPDM composites. An excellent self-supporting property of the EPDM composites was obtained by combining the formation of the AF network and the formation of crystalline phases at higher temperature (above 600 °C). The thermal shrinkage performance of AF and the increased thermal stability of the EPDM composites improved the ceramifiable properties of the EPDM composites.
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spelling doaj.art-51fee5ae688742c3a142219f691d4a552023-11-20T06:18:08ZengMDPI AGPolymers2073-43602020-07-01127152310.3390/polym12071523Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid FiberDong Zhao0Wei Liu1Yucai Shen2Guodong Jiang3Tingwei Wang4College of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Material Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCeramifiable ethylene propylene diene monomer (EPDM) composites with fiber network structures were prepared by using aramid fiber (AF), ammonium polyphosphate (APP), and silicate glass frits (SGF). The effect of AF on the curing characteristic of the ceramifiable EPDM composites was studied. The morphology of AF in the composites system was observed by optical microscopy (OM) and scanning electron microscope (SEM). The effects of the observed AF network structures on the solvent resistance, mechanical properties, ablative resistance, self-supporting property, and ceramifiable properties of the composites were investigated. Results suggested that the existence of the AF network structure improved the vulcanization properties, solvent resistance, thermal stability, and ablative resistance of the EPDM composites. An excellent self-supporting property of the EPDM composites was obtained by combining the formation of the AF network and the formation of crystalline phases at higher temperature (above 600 °C). The thermal shrinkage performance of AF and the increased thermal stability of the EPDM composites improved the ceramifiable properties of the EPDM composites.https://www.mdpi.com/2073-4360/12/7/1523EPDMceramifiablearamid fiberself-supportingthermal stability
spellingShingle Dong Zhao
Wei Liu
Yucai Shen
Guodong Jiang
Tingwei Wang
Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
Polymers
EPDM
ceramifiable
aramid fiber
self-supporting
thermal stability
title Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
title_full Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
title_fullStr Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
title_full_unstemmed Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
title_short Improved Self-Supporting and Ceramifiable Properties of Ceramifiable EPDM Composites by Adding Aramid Fiber
title_sort improved self supporting and ceramifiable properties of ceramifiable epdm composites by adding aramid fiber
topic EPDM
ceramifiable
aramid fiber
self-supporting
thermal stability
url https://www.mdpi.com/2073-4360/12/7/1523
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AT yucaishen improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber
AT guodongjiang improvedselfsupportingandceramifiablepropertiesofceramifiableepdmcompositesbyaddingaramidfiber
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