Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology
The title compound, {[Ni(C14H18O4)(C11H9N3O)]·H2O}n, contains octahedrally coordinated NiII ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni2(OCO)2] dimer...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2023-10-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623008696 |
| _version_ | 1797635669418311680 |
|---|---|
| author | Jamelah Z. Travis Robert L. LaDuca |
| author_facet | Jamelah Z. Travis Robert L. LaDuca |
| author_sort | Jamelah Z. Travis |
| collection | DOAJ |
| description | The title compound, {[Ni(C14H18O4)(C11H9N3O)]·H2O}n, contains octahedrally coordinated NiII ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni2(OCO)2] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H...O supramolecular interactions between ada ligands and water molecules of crystallization to form the full triperiodic crystal structure of the title compound. |
| first_indexed | 2024-03-11T12:23:41Z |
| format | Article |
| id | doaj.art-52079983d5764ea7b07a8a2e7b91323d |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-03-11T12:23:41Z |
| publishDate | 2023-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-52079983d5764ea7b07a8a2e7b91323d2023-11-06T14:47:30ZengInternational Union of CrystallographyIUCrData2414-31462023-10-01810x23086910.1107/S2414314623008696bh4079Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topologyJamelah Z. Travis0Robert L. LaDuca1Department of Chemistry, Hope College, Holland, MI 49423, USAE-194 Holmes Hall, Michigan State University, Lyman Briggs College, 919 E. Shaw Lane, East Lansing, MI 48825, USAThe title compound, {[Ni(C14H18O4)(C11H9N3O)]·H2O}n, contains octahedrally coordinated NiII ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni2(OCO)2] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C—H...O supramolecular interactions between ada ligands and water molecules of crystallization to form the full triperiodic crystal structure of the title compound.http://scripts.iucr.org/cgi-bin/paper?S2414314623008696crystal structurepolymertopologynickelisonicotinamide |
| spellingShingle | Jamelah Z. Travis Robert L. LaDuca Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology IUCrData crystal structure polymer topology nickel isonicotinamide |
| title | Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
| title_full | Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
| title_fullStr | Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
| title_full_unstemmed | Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
| title_short | Poly[[(μ3-adamantane-1,3-diacetato)[μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology |
| title_sort | poly μ3 adamantane 1 3 diacetato μ n pyridin 3 yl isonicotinamide nickel ii monohydrate a layered coordination polymer with triangular 3 6 topology |
| topic | crystal structure polymer topology nickel isonicotinamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623008696 |
| work_keys_str_mv | AT jamelahztravis polym3adamantane13diacetatomnpyridin3ylisonicotinamidenickeliimonohydratealayeredcoordinationpolymerwithtriangular36topology AT robertlladuca polym3adamantane13diacetatomnpyridin3ylisonicotinamidenickeliimonohydratealayeredcoordinationpolymerwithtriangular36topology |