Temperature dependence of adsorption hysteresis in flexible metal organic frameworks
Flexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to descr...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2020-12-01
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| Series: | Communications Chemistry |
| Online Access: | https://doi.org/10.1038/s42004-020-00429-3 |
| _version_ | 1818749314497773568 |
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| author | Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May |
| author_facet | Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May |
| author_sort | Shamsur Rahman |
| collection | DOAJ |
| description | Flexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to describe hysteretic MOF sorption isotherms and determine their temperature dependence, which is asymptotic at low temperatures. |
| first_indexed | 2024-12-18T04:01:49Z |
| format | Article |
| id | doaj.art-520c138026c74ba0bd49301bcc7ff8e3 |
| institution | Directory Open Access Journal |
| issn | 2399-3669 |
| language | English |
| last_indexed | 2024-12-18T04:01:49Z |
| publishDate | 2020-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Communications Chemistry |
| spelling | doaj.art-520c138026c74ba0bd49301bcc7ff8e32022-12-21T21:21:41ZengNature PortfolioCommunications Chemistry2399-36692020-12-01311610.1038/s42004-020-00429-3Temperature dependence of adsorption hysteresis in flexible metal organic frameworksShamsur Rahman0Arash Arami-Niya1Xiaoxian Yang2Gongkui Xiao3Gang (Kevin) Li4Eric F. May5Fluid Science & Resources Division, School of Engineering, University of Western AustraliaFluid Science & Resources Division, School of Engineering, University of Western AustraliaFluid Science & Resources Division, School of Engineering, University of Western AustraliaFluid Science & Resources Division, School of Engineering, University of Western AustraliaFluid Science & Resources Division, School of Engineering, University of Western AustraliaFluid Science & Resources Division, School of Engineering, University of Western AustraliaFlexible metal–organic frameworks that undergo structural transformations upon gas sorption show great promise for applications in gas storage and separation, but accurately describing their stepped isotherms and hysteresis remains a challenge. Here, the authors introduce an empirical model to describe hysteretic MOF sorption isotherms and determine their temperature dependence, which is asymptotic at low temperatures.https://doi.org/10.1038/s42004-020-00429-3 |
| spellingShingle | Shamsur Rahman Arash Arami-Niya Xiaoxian Yang Gongkui Xiao Gang (Kevin) Li Eric F. May Temperature dependence of adsorption hysteresis in flexible metal organic frameworks Communications Chemistry |
| title | Temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| title_full | Temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| title_fullStr | Temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| title_full_unstemmed | Temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| title_short | Temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| title_sort | temperature dependence of adsorption hysteresis in flexible metal organic frameworks |
| url | https://doi.org/10.1038/s42004-020-00429-3 |
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