THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT
The iodate-selective electrode based on the principle of precipitation reaction could be made by coating the platinum wire with silver iodate (AgIO3). In this research was carried out optimization the iodate-selective electrode using chitosan membrane as an AgIO3 support. The AgIO3 were added in the...
Main Authors: | , , |
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Format: | Article |
Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2010-06-01
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Series: | Indonesian Journal of Chemistry |
Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/21670 |
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author | Ani Mulyasuryani Qonitah Fardiyah Rizki Sugiri |
author_facet | Ani Mulyasuryani Qonitah Fardiyah Rizki Sugiri |
author_sort | Ani Mulyasuryani |
collection | DOAJ |
description | The iodate-selective electrode based on the principle of precipitation reaction could be made by coating the platinum wire with silver iodate (AgIO3). In this research was carried out optimization the iodate-selective electrode using chitosan membrane as an AgIO3 support. The AgIO3 were added in the 2 mL 1% chitosan solution, is 0.5 to 2.5 % (w/v). The thickness of the membrane used is 6 to 12 µm. The electrode cell potential is measured against Ag/AgCl electrode as a reference electrode. The optimum electrode performance was at 2.0 % of AgIO3 with thickness a membrane of 10 µm. The iodate-selective electrode has a Nernstian factor is 52.96 mV/decade and a response time of 10 seconds. The concentration range was determined from 10-3 M to 10-1 M and the detection limit is 1.12 x 10-5 M.
Keywords: Ion Selective Electrode, Iodate, Chitosan Membrane |
first_indexed | 2024-12-21T07:03:11Z |
format | Article |
id | doaj.art-520e894ea84f4d0ba99ab3b2eca8f81d |
institution | Directory Open Access Journal |
issn | 1411-9420 2460-1578 |
language | English |
last_indexed | 2024-12-21T07:03:11Z |
publishDate | 2010-06-01 |
publisher | Department of Chemistry, Universitas Gadjah Mada |
record_format | Article |
series | Indonesian Journal of Chemistry |
spelling | doaj.art-520e894ea84f4d0ba99ab3b2eca8f81d2022-12-21T19:12:10ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782010-06-017328428710.22146/ijc.2167014768THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORTAni Mulyasuryani0Qonitah Fardiyah1Rizki Sugiri2Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University Jl. MT Haryono, Malang, IndonesiaThe iodate-selective electrode based on the principle of precipitation reaction could be made by coating the platinum wire with silver iodate (AgIO3). In this research was carried out optimization the iodate-selective electrode using chitosan membrane as an AgIO3 support. The AgIO3 were added in the 2 mL 1% chitosan solution, is 0.5 to 2.5 % (w/v). The thickness of the membrane used is 6 to 12 µm. The electrode cell potential is measured against Ag/AgCl electrode as a reference electrode. The optimum electrode performance was at 2.0 % of AgIO3 with thickness a membrane of 10 µm. The iodate-selective electrode has a Nernstian factor is 52.96 mV/decade and a response time of 10 seconds. The concentration range was determined from 10-3 M to 10-1 M and the detection limit is 1.12 x 10-5 M. Keywords: Ion Selective Electrode, Iodate, Chitosan Membranehttps://jurnal.ugm.ac.id/ijc/article/view/21670 |
spellingShingle | Ani Mulyasuryani Qonitah Fardiyah Rizki Sugiri THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT Indonesian Journal of Chemistry |
title | THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT |
title_full | THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT |
title_fullStr | THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT |
title_full_unstemmed | THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT |
title_short | THE PREPARATION OF AN IODATE SELECTIVE ELECTRODE USING SILVER IODATE AS THE ACTIVE AGENT IN A CHITOSAN SUPPORT |
title_sort | preparation of an iodate selective electrode using silver iodate as the active agent in a chitosan support |
url | https://jurnal.ugm.ac.id/ijc/article/view/21670 |
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