Sessile drops in weightlessness: an ideal playground for challenging Young’s equation

Abstract Sessile drop creation in weightlessness is critical for designing scientific instruments for space applications and for manipulating organic or biological liquids, such as whole human blood or DNA drops. It requires perfect control of injection, spreading, and wetting; however, the simple a...

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Main Authors: Marc Medale, David Brutin
Format: Article
Language:English
Published: Nature Portfolio 2021-08-01
Series:npj Microgravity
Online Access:https://doi.org/10.1038/s41526-021-00153-9
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author Marc Medale
David Brutin
author_facet Marc Medale
David Brutin
author_sort Marc Medale
collection DOAJ
description Abstract Sessile drop creation in weightlessness is critical for designing scientific instruments for space applications and for manipulating organic or biological liquids, such as whole human blood or DNA drops. It requires perfect control of injection, spreading, and wetting; however, the simple act of creating a drop on a substrate is more complex than it appears. A new macroscopic model is derived to better understand this related behavior. We find that, for a given set of substrate, liquid, and surrounding gas properties, when the ratio of surface free energies to contact line free energy is on the macroscopic scale, the macroscopic contact angle can vary at static equilibrium over a broad volume range. It can increase or decrease against volume depending on the sign of this ratio up to an asymptotic value. Consequently, our model aims to explore configurations that challenge the faithful representativity of the classical Young’s equation and extends the present understanding of wetting.
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spelling doaj.art-521943ff83ae440f907d5b807871aa952023-11-02T11:19:34ZengNature Portfolionpj Microgravity2373-80652021-08-01711910.1038/s41526-021-00153-9Sessile drops in weightlessness: an ideal playground for challenging Young’s equationMarc Medale0David Brutin1Aix Marseille Université, CNRS, IUSTIAix Marseille Université, CNRS, IUSTIAbstract Sessile drop creation in weightlessness is critical for designing scientific instruments for space applications and for manipulating organic or biological liquids, such as whole human blood or DNA drops. It requires perfect control of injection, spreading, and wetting; however, the simple act of creating a drop on a substrate is more complex than it appears. A new macroscopic model is derived to better understand this related behavior. We find that, for a given set of substrate, liquid, and surrounding gas properties, when the ratio of surface free energies to contact line free energy is on the macroscopic scale, the macroscopic contact angle can vary at static equilibrium over a broad volume range. It can increase or decrease against volume depending on the sign of this ratio up to an asymptotic value. Consequently, our model aims to explore configurations that challenge the faithful representativity of the classical Young’s equation and extends the present understanding of wetting.https://doi.org/10.1038/s41526-021-00153-9
spellingShingle Marc Medale
David Brutin
Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
npj Microgravity
title Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
title_full Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
title_fullStr Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
title_full_unstemmed Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
title_short Sessile drops in weightlessness: an ideal playground for challenging Young’s equation
title_sort sessile drops in weightlessness an ideal playground for challenging young s equation
url https://doi.org/10.1038/s41526-021-00153-9
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AT davidbrutin sessiledropsinweightlessnessanidealplaygroundforchallengingyoungsequation