Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies
The presence of pharmaceuticals in water systems threatens both terrestrial and aquatic life across the globe. Some of such contaminants are β-blockers and anticonvulsants, which have been constantly detected in different water systems. Various methodologies have been introduced for the removal of t...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-10-01
|
| Series: | Gels |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2310-2861/7/4/190 |
| _version_ | 1797504340523483136 |
|---|---|
| author | Phodiso Prudence Mashile Philiswa Nosizo Nomngongo |
| author_facet | Phodiso Prudence Mashile Philiswa Nosizo Nomngongo |
| author_sort | Phodiso Prudence Mashile |
| collection | DOAJ |
| description | The presence of pharmaceuticals in water systems threatens both terrestrial and aquatic life across the globe. Some of such contaminants are β-blockers and anticonvulsants, which have been constantly detected in different water systems. Various methodologies have been introduced for the removal of these emerging pollutants from different waters. Among them, adsorption using nanomaterials has proved to be an efficient and cost-effective process for the removal of pharmaceuticals from contaminated water. In this this study, a firsthand/time approach applying a recyclable magnetic cellulose-chitosan nanocomposite for effective simultaneous removal of two β-blockers (atenolol (ATN)) and propranolol (PRP) and an anticonvulsant (carbamazepine (CBZ)) is reported. A detailed characterization of the eco-friendly, biocompatible cellulose-chitosan nanocomposite with magnetic properties was performed at various rates of synthesis using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and Fourier transform infrared (FTIR) spectroscopy. A N<sub>2c</sub> adsorption-desorption test showed that the prepared nanocomposite is mesoporous, with a BET area of 112 m<sup>2</sup> g<sup>−1</sup>. The BET isotherms results showed that the magnetic cellulose-chitosan nanocomposite has a pore size of 24.1 nm. The adsorption equilibrium of PRP and CBZ fitted with the Langmuir isotherm was consistent with the highest coefficient of determination (R<sup>2</sup> = 0.9945) and (R<sup>2</sup> = 0.9942), respectively, while the Sips model provided a better fit for ATN, with a coefficient of determination R<sup>2</sup> = 0.9956. The adsorption rate was accompanied by a pseudo-second-order kinetics. Moreover, the swelling test showed that up to 100 percent swelling of the magnetic cellulose-chitosan nanocomposite was achieved. |
| first_indexed | 2024-03-10T04:03:15Z |
| format | Article |
| id | doaj.art-525acbafeab74e329f0785a06b6daa0a |
| institution | Directory Open Access Journal |
| issn | 2310-2861 |
| language | English |
| last_indexed | 2024-03-10T04:03:15Z |
| publishDate | 2021-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Gels |
| spelling | doaj.art-525acbafeab74e329f0785a06b6daa0a2023-11-23T08:27:44ZengMDPI AGGels2310-28612021-10-017419010.3390/gels7040190Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium StudiesPhodiso Prudence Mashile0Philiswa Nosizo Nomngongo1Department of Chemical Sciences, Doornfontein Campus, University of Johannesburg, P.O. Box 17011, Doornfontein 2028, South AfricaDepartment of Chemical Sciences, Doornfontein Campus, University of Johannesburg, P.O. Box 17011, Doornfontein 2028, South AfricaThe presence of pharmaceuticals in water systems threatens both terrestrial and aquatic life across the globe. Some of such contaminants are β-blockers and anticonvulsants, which have been constantly detected in different water systems. Various methodologies have been introduced for the removal of these emerging pollutants from different waters. Among them, adsorption using nanomaterials has proved to be an efficient and cost-effective process for the removal of pharmaceuticals from contaminated water. In this this study, a firsthand/time approach applying a recyclable magnetic cellulose-chitosan nanocomposite for effective simultaneous removal of two β-blockers (atenolol (ATN)) and propranolol (PRP) and an anticonvulsant (carbamazepine (CBZ)) is reported. A detailed characterization of the eco-friendly, biocompatible cellulose-chitosan nanocomposite with magnetic properties was performed at various rates of synthesis using X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), and Fourier transform infrared (FTIR) spectroscopy. A N<sub>2c</sub> adsorption-desorption test showed that the prepared nanocomposite is mesoporous, with a BET area of 112 m<sup>2</sup> g<sup>−1</sup>. The BET isotherms results showed that the magnetic cellulose-chitosan nanocomposite has a pore size of 24.1 nm. The adsorption equilibrium of PRP and CBZ fitted with the Langmuir isotherm was consistent with the highest coefficient of determination (R<sup>2</sup> = 0.9945) and (R<sup>2</sup> = 0.9942), respectively, while the Sips model provided a better fit for ATN, with a coefficient of determination R<sup>2</sup> = 0.9956. The adsorption rate was accompanied by a pseudo-second-order kinetics. Moreover, the swelling test showed that up to 100 percent swelling of the magnetic cellulose-chitosan nanocomposite was achieved.https://www.mdpi.com/2310-2861/7/4/190hydrogelswellingpropranololatenololcarbamazepinewater system |
| spellingShingle | Phodiso Prudence Mashile Philiswa Nosizo Nomngongo Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies Gels hydrogel swelling propranolol atenolol carbamazepine water system |
| title | Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies |
| title_full | Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies |
| title_fullStr | Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies |
| title_full_unstemmed | Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies |
| title_short | Magnetic Cellulose-Chitosan Nanocomposite for Simultaneous Removal of Emerging Contaminants: Adsorption Kinetics and Equilibrium Studies |
| title_sort | magnetic cellulose chitosan nanocomposite for simultaneous removal of emerging contaminants adsorption kinetics and equilibrium studies |
| topic | hydrogel swelling propranolol atenolol carbamazepine water system |
| url | https://www.mdpi.com/2310-2861/7/4/190 |
| work_keys_str_mv | AT phodisoprudencemashile magneticcellulosechitosannanocompositeforsimultaneousremovalofemergingcontaminantsadsorptionkineticsandequilibriumstudies AT philiswanosizonomngongo magneticcellulosechitosannanocompositeforsimultaneousremovalofemergingcontaminantsadsorptionkineticsandequilibriumstudies |