[Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II)
The title compound, [WCl2(C9H10N2S2)(CO)3], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 1...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811038104 |
| _version_ | 1818975375571550208 |
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| author | Helgard G. Raubenheimer Stephanie Cronje Christoph E. Strasser |
| author_facet | Helgard G. Raubenheimer Stephanie Cronje Christoph E. Strasser |
| author_sort | Helgard G. Raubenheimer |
| collection | DOAJ |
| description | The title compound, [WCl2(C9H10N2S2)(CO)3], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis(4-methyl-1,3-thiazol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, molecules are linked into chains parallel to [201] by weak C—H...O contacts between the CH2 group of the bis(4-methylthiazol-2-yl)methane ligand and the O atom of the capping CO group. |
| first_indexed | 2024-12-20T15:54:57Z |
| format | Article |
| id | doaj.art-52615c2c931e43a6a2bb905e943bf38f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:54:57Z |
| publishDate | 2011-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-52615c2c931e43a6a2bb905e943bf38f2022-12-21T19:34:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1460m146010.1107/S1600536811038104[Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II)Helgard G. RaubenheimerStephanie CronjeChristoph E. StrasserThe title compound, [WCl2(C9H10N2S2)(CO)3], is a heptacoordinate tungsten(II) complex with a capped–octahedral coordination sphere in which one CO ligand caps a face formed by a chloro ligand and the two other carbonyls. The chloro ligands are mutually trans positioned at an angle of 156.98 (7)°. The chelating bis(4-methyl-1,3-thiazol-2-yl)methane ligand coordinates with the imine N atoms. In the crystal, molecules are linked into chains parallel to [201] by weak C—H...O contacts between the CH2 group of the bis(4-methylthiazol-2-yl)methane ligand and the O atom of the capping CO group.http://scripts.iucr.org/cgi-bin/paper?S1600536811038104 |
| spellingShingle | Helgard G. Raubenheimer Stephanie Cronje Christoph E. Strasser [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) Acta Crystallographica Section E |
| title | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
| title_full | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
| title_fullStr | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
| title_full_unstemmed | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
| title_short | [Bis(4-methyl-1,3-thiazol-2-yl-κN)methane]tricarbonyldichloridotungsten(II) |
| title_sort | bis 4 methyl 1 3 thiazol 2 yl amp 954 n methane tricarbonyldichloridotungsten ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811038104 |
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