Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance

The cover systems in contaminated sites have some problems, including desiccation cracks, which would lead to degradation of the barrier performance. This study presented a systemic laboratory experimental investigation on the liquid–plastic limit, moisture retention, hydraulic conductivity (<i&g...

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Main Authors: Min Wang, Jiaming Wen, Heng Zhuang, Weiyi Xia, Ningjun Jiang, Yanjun Du
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/12/14/7341
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author Min Wang
Jiaming Wen
Heng Zhuang
Weiyi Xia
Ningjun Jiang
Yanjun Du
author_facet Min Wang
Jiaming Wen
Heng Zhuang
Weiyi Xia
Ningjun Jiang
Yanjun Du
author_sort Min Wang
collection DOAJ
description The cover systems in contaminated sites have some problems, including desiccation cracks, which would lead to degradation of the barrier performance. This study presented a systemic laboratory experimental investigation on the liquid–plastic limit, moisture retention, hydraulic conductivity (<i>k</i>), and gas diffusion barrier properties of amended compacted clay by attapulgite and diatomite for controlling desiccation cracks and migration of water and volatile organic compounds (VOCs). The results showed that the attapulgite could enhance the moisture retention and liquid limit of amended compacted clay. Diatomite could reduce the gas diffusion coefficient (<i>D<sub>θ</sub></i>) significantly. The compacted clay amended by the dual-additives component of attapulgite and diatomite could enhance the liquid limit, moisture retention percent, gas barrier property, and hydraulic performance compared with the unamended clay. Based on the experimental data obtained, the dosage of additives was targeted to be 5%. The moisture retention percent of dual-additives (attapulgite 4% and diatomite 1%) amended clay increased by 82%, the <i>k</i> decreased by 25%, and the <i>D<sub>θ</sub></i> decreased by 42% compared with unamended clay. Scanning electron microscopy (SEM), BET-specific surface area test method (BET), Mercury Intrusion Porosimetry (MIP), and thermogravimetric analysis (TGA) indicated the enhancement mechanism of additives-amended compacted clay.
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spelling doaj.art-526c0a93524b40cc82786d3957dbfe4f2023-11-30T22:46:07ZengMDPI AGApplied Sciences2076-34172022-07-011214734110.3390/app12147341Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention PerformanceMin Wang0Jiaming Wen1Heng Zhuang2Weiyi Xia3Ningjun Jiang4Yanjun Du5Jiangsu Key Laboratory of Urban Underground Engineering & Environmental Safety, Institute of Geotechnical Engineering, Southeast University, Nanjing 210096, ChinaZijin (Changsha) Engineering Technology Co., Ltd., Changsha 410006, ChinaJiangsu Key Laboratory of Urban Underground Engineering & Environmental Safety, Institute of Geotechnical Engineering, Southeast University, Nanjing 210096, ChinaJiangsu Environmental Engineering Technology Co., Ltd., Nanjing 210019, ChinaJiangsu Key Laboratory of Urban Underground Engineering & Environmental Safety, Institute of Geotechnical Engineering, Southeast University, Nanjing 210096, ChinaJiangsu Key Laboratory of Urban Underground Engineering & Environmental Safety, Institute of Geotechnical Engineering, Southeast University, Nanjing 210096, ChinaThe cover systems in contaminated sites have some problems, including desiccation cracks, which would lead to degradation of the barrier performance. This study presented a systemic laboratory experimental investigation on the liquid–plastic limit, moisture retention, hydraulic conductivity (<i>k</i>), and gas diffusion barrier properties of amended compacted clay by attapulgite and diatomite for controlling desiccation cracks and migration of water and volatile organic compounds (VOCs). The results showed that the attapulgite could enhance the moisture retention and liquid limit of amended compacted clay. Diatomite could reduce the gas diffusion coefficient (<i>D<sub>θ</sub></i>) significantly. The compacted clay amended by the dual-additives component of attapulgite and diatomite could enhance the liquid limit, moisture retention percent, gas barrier property, and hydraulic performance compared with the unamended clay. Based on the experimental data obtained, the dosage of additives was targeted to be 5%. The moisture retention percent of dual-additives (attapulgite 4% and diatomite 1%) amended clay increased by 82%, the <i>k</i> decreased by 25%, and the <i>D<sub>θ</sub></i> decreased by 42% compared with unamended clay. Scanning electron microscopy (SEM), BET-specific surface area test method (BET), Mercury Intrusion Porosimetry (MIP), and thermogravimetric analysis (TGA) indicated the enhancement mechanism of additives-amended compacted clay.https://www.mdpi.com/2076-3417/12/14/7341additivescompacted clay covermoisture retentiongas diffusion barrierhydraulic conductivity
spellingShingle Min Wang
Jiaming Wen
Heng Zhuang
Weiyi Xia
Ningjun Jiang
Yanjun Du
Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
Applied Sciences
additives
compacted clay cover
moisture retention
gas diffusion barrier
hydraulic conductivity
title Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
title_full Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
title_fullStr Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
title_full_unstemmed Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
title_short Screening Additives for Amending Compacted Clay Covers to Enhance Diffusion Barrier Properties and Moisture Retention Performance
title_sort screening additives for amending compacted clay covers to enhance diffusion barrier properties and moisture retention performance
topic additives
compacted clay cover
moisture retention
gas diffusion barrier
hydraulic conductivity
url https://www.mdpi.com/2076-3417/12/14/7341
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AT hengzhuang screeningadditivesforamendingcompactedclaycoverstoenhancediffusionbarrierpropertiesandmoistureretentionperformance
AT weiyixia screeningadditivesforamendingcompactedclaycoverstoenhancediffusionbarrierpropertiesandmoistureretentionperformance
AT ningjunjiang screeningadditivesforamendingcompactedclaycoverstoenhancediffusionbarrierpropertiesandmoistureretentionperformance
AT yanjundu screeningadditivesforamendingcompactedclaycoverstoenhancediffusionbarrierpropertiesandmoistureretentionperformance