5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C15H10FIO2S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crys...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809030992 |
| _version_ | 1818791677627727872 |
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| author | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_facet | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_sort | Hong Dae Choi |
| collection | DOAJ |
| description | In the title compound, C15H10FIO2S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crystal structure is stabilized by an intermolecular C—H...O hydrogen bond and an I...O halogen bond [3.055 (2) Å]. The crystal structure also exhibits an intermolecular C—H...π interaction between the methyl H atom and the 4-iodophenyl ring of an adjacent benzofuran molecule, and aromatic π–π interactions between the benzene rings of neighbouring benzofuran systems [centroid–centroid distance = 3.558 (3) Å]. |
| first_indexed | 2024-12-18T15:15:09Z |
| format | Article |
| id | doaj.art-52bf7f9da4504f38a7d29e2ff5d27d11 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:15:09Z |
| publishDate | 2009-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-52bf7f9da4504f38a7d29e2ff5d27d112022-12-21T21:03:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659o2115o211510.1107/S16005368090309925-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuranHong Dae ChoiPil Ja SeoByeng Wha SonUk LeeIn the title compound, C15H10FIO2S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodophenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crystal structure is stabilized by an intermolecular C—H...O hydrogen bond and an I...O halogen bond [3.055 (2) Å]. The crystal structure also exhibits an intermolecular C—H...π interaction between the methyl H atom and the 4-iodophenyl ring of an adjacent benzofuran molecule, and aromatic π–π interactions between the benzene rings of neighbouring benzofuran systems [centroid–centroid distance = 3.558 (3) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809030992 |
| spellingShingle | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran Acta Crystallographica Section E |
| title | 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran |
| title_full | 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran |
| title_fullStr | 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran |
| title_full_unstemmed | 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran |
| title_short | 5-Fluoro-2-(4-iodophenyl)-3-methylsulfinyl-1-benzofuran |
| title_sort | 5 fluoro 2 4 iodophenyl 3 methylsulfinyl 1 benzofuran |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809030992 |
| work_keys_str_mv | AT hongdaechoi 5fluoro24iodophenyl3methylsulfinyl1benzofuran AT piljaseo 5fluoro24iodophenyl3methylsulfinyl1benzofuran AT byengwhason 5fluoro24iodophenyl3methylsulfinyl1benzofuran AT uklee 5fluoro24iodophenyl3methylsulfinyl1benzofuran |