Structure Formation and Properties of Concrete Based on Organic Hydraulic Binders

The article addresses the issues of structure formation of road composite materials containing hydraulic (рortland cement) and organic (bitumen) binders. It has been determined that organic and hydraulic binders, being thermodynamically incompatible, are capable of interaction and complement each ot...

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Bibliographic Details
Main Authors: B. M. Khroustalev, U. A. Veranko, V. V. Zankavich, Yu. G. Aliakseyeu, Yue Xuejun, Bo Shang, Jicun Shi
Format: Article
Language:Russian
Published: Belarusian National Technical University 2020-06-01
Series:Nauka i Tehnika
Subjects:
Online Access:https://sat.bntu.by/jour/article/view/2315
Description
Summary:The article addresses the issues of structure formation of road composite materials containing hydraulic (рortland cement) and organic (bitumen) binders. It has been determined that organic and hydraulic binders, being thermodynamically incompatible, are capable of interaction and complement each other. Structure formation processes are associated with interphase transition layers interaction mechanism and the direct formation of phase contacts with cement crystallohydrates. The interphase boundary is diffuse and is established through interphase transition layers. The emergence of interfacial layers is thermodynamically advantageous, since it contributes to a decrease in Gibbs free energy and does not contradict modern concepts of solid state physics. It was established that with cement content of about 30 % of complex bitumen-cement binder volume, there will appear (nucleate) phase contacts that will prevail in the binder structure when the cement content is more than 60 %. In the case phase contacts prevail, concrete will demonstrate significant strength at high temperatures, but low temperature and fatigue crack resistance, which will lead to their durability loss. The cement content of 30–40 % of the total complex binder can be considered optimal.
ISSN:2227-1031
2414-0392