Bis[N′-(2-oxo-1H-indol-3-ylidene)thiophene-2-carbohydrazidato-κ3O,N′,O′]zinc(II) N,N-dimethylformide monosolvate monohydrate
The metal atom of the title compound, [Zn(C13H8N3O2S)2]·C3H7NO·H2O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and un...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810039504 |
| Summary: | The metal atom of the title compound, [Zn(C13H8N3O2S)2]·C3H7NO·H2O, is O,N,O′-chelated by two deprotonated Schiff bases and it exists in a distorted octahedral geometry. The N–H groups of the ligands, the carbonyl group of the DMF molecule and uncoordinated water molecule engage in N—H...O and O—H...O interactions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. |
|---|---|
| ISSN: | 1600-5368 |