Directive emission from polymeric fluorophore with epsilon-near-zero squaraine molecular film

Enhanced directionality of photoluminescence emission has attracted attention due to its diverse application areas ranging from single-photon sources to fluorescence sensing and bio-imaging. Utilization of null phase advance in epsilon-near-zero (ENZ) medium is an important scheme to achieve the dir...

Full description

Bibliographic Details
Main Authors: Choi Kyu-Ri, Kim Minjae, Wu Jeong Weon, D’Aléo Anthony, Lee Yeon Ui
Format: Article
Language:English
Published: De Gruyter 2023-04-01
Series:Nanophotonics
Subjects:
Online Access:https://doi.org/10.1515/nanoph-2022-0763
Description
Summary:Enhanced directionality of photoluminescence emission has attracted attention due to its diverse application areas ranging from single-photon sources to fluorescence sensing and bio-imaging. Utilization of null phase advance in epsilon-near-zero (ENZ) medium is an important scheme to achieve the directive emission. Despite various designs proposed for ENZ-based directive emission, most of the ENZ mediums are restricted to subwavelength structures of metallic plasmonics or inorganic dielectrics. Here, we introduce an organic ENZ film placed on top of a polymeric fluorophore film to demonstrate a directive emission. By taking advantage of the structural coherence in the P3HT film and the ENZ response in the squaraine molecular film, 42 % increase in directive emission is achieved. Capability to control directive emission with organic ENZ films is highly useful in applications requiring bio-compatibility of a fluorophore-embedding medium.
ISSN:2192-8614