Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride

Microplastics (MPs) are an issue of prime environmental concern globally. The abundance of MP particles in the informal open solid waste landfill soil was evaluated showing 180–1120 MP particles per kg of soil. Moisture content (MC), electrical conductivity (EC) and pH of the MP-contaminated soil co...

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Main Authors: S. Mahesh, Nisarga K. Gowda, Sahana Mahesh
Format: Article
Language:English
Published: IWA Publishing 2023-01-01
Series:Water Science and Technology
Subjects:
Online Access:http://wst.iwaponline.com/content/87/1/115
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author S. Mahesh
Nisarga K. Gowda
Sahana Mahesh
author_facet S. Mahesh
Nisarga K. Gowda
Sahana Mahesh
author_sort S. Mahesh
collection DOAJ
description Microplastics (MPs) are an issue of prime environmental concern globally. The abundance of MP particles in the informal open solid waste landfill soil was evaluated showing 180–1120 MP particles per kg of soil. Moisture content (MC), electrical conductivity (EC) and pH of the MP-contaminated soil compared to the baseline showed 2.96% MC, 187–441 μS/cm EC and 6.94 pH. Morphology of extracted MPs in SEM showed particle fragmentation as film fragments (13.7%), fragments (56.1%), fibres (26.4%) and foam (3.8%). EDS results showed Carbon 71.8% and 24.5% oxygen with traces of Na, Al, Si and Cl−. FTIR of field obtained MPs identified were polyethylene and polypropylene. The association of MP particles with COD and chloride was discovered. MP particles of Low-density Polyethylene of size of 1 mm × 1 mm and thickness 25 μm up to 20 numbers showed no effect adding to the COD values. The COD values increased with increase in MP particle numbers. Similarly, chloride associations with MP particles showed an increase in MP particles reducing chloride values by 31% in landfill runoff water. It is interpreted that MP particle disintegration into nano-sized plastics (NPs) in the soil/runoff water can greatly increase the COD values and impair the salt mass balance. HIGHLIGHTS Municipal urban informal landfill soil was evaluated for abundance of MP particles.; The associated environmental parameters like pH, EC, TDS were evaluated.; SEM, EDS, FT-IR were used to understand the analytics and morphology of the extracted MPs.; MP associations with COD and chloride are established for the first time.;
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spelling doaj.art-53365879e03c4189a3e16ba478823bbe2023-02-17T16:42:18ZengIWA PublishingWater Science and Technology0273-12231996-97322023-01-0187111512910.2166/wst.2022.412412Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chlorideS. Mahesh0Nisarga K. Gowda1Sahana Mahesh2 Department of Environmental Engineering, Sri Jayachamarajendra College of Engineering, Constituent College of JSS Science and Technology University (Formerly SJCE), JSSTI Campus, Mysuru, Karnataka State 570006, India Department of Environmental Engineering, Sri Jayachamarajendra College of Engineering, Constituent College of JSS Science and Technology University (Formerly SJCE), JSSTI Campus, Mysuru, Karnataka State 570006, India Department of Environmental Engineering, Sri Jayachamarajendra College of Engineering, Constituent College of JSS Science and Technology University (Formerly SJCE), JSSTI Campus, Mysuru, Karnataka State 570006, India Microplastics (MPs) are an issue of prime environmental concern globally. The abundance of MP particles in the informal open solid waste landfill soil was evaluated showing 180–1120 MP particles per kg of soil. Moisture content (MC), electrical conductivity (EC) and pH of the MP-contaminated soil compared to the baseline showed 2.96% MC, 187–441 μS/cm EC and 6.94 pH. Morphology of extracted MPs in SEM showed particle fragmentation as film fragments (13.7%), fragments (56.1%), fibres (26.4%) and foam (3.8%). EDS results showed Carbon 71.8% and 24.5% oxygen with traces of Na, Al, Si and Cl−. FTIR of field obtained MPs identified were polyethylene and polypropylene. The association of MP particles with COD and chloride was discovered. MP particles of Low-density Polyethylene of size of 1 mm × 1 mm and thickness 25 μm up to 20 numbers showed no effect adding to the COD values. The COD values increased with increase in MP particle numbers. Similarly, chloride associations with MP particles showed an increase in MP particles reducing chloride values by 31% in landfill runoff water. It is interpreted that MP particle disintegration into nano-sized plastics (NPs) in the soil/runoff water can greatly increase the COD values and impair the salt mass balance. HIGHLIGHTS Municipal urban informal landfill soil was evaluated for abundance of MP particles.; The associated environmental parameters like pH, EC, TDS were evaluated.; SEM, EDS, FT-IR were used to understand the analytics and morphology of the extracted MPs.; MP associations with COD and chloride are established for the first time.;http://wst.iwaponline.com/content/87/1/115cod and chloride associations with mpsedslandfillldpemicroplasticssem
spellingShingle S. Mahesh
Nisarga K. Gowda
Sahana Mahesh
Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
Water Science and Technology
cod and chloride associations with mps
eds
landfill
ldpe
microplastics
sem
title Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
title_full Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
title_fullStr Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
title_full_unstemmed Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
title_short Identification of microplastics from urban informal solid waste landfill soil; MP associations with COD and chloride
title_sort identification of microplastics from urban informal solid waste landfill soil mp associations with cod and chloride
topic cod and chloride associations with mps
eds
landfill
ldpe
microplastics
sem
url http://wst.iwaponline.com/content/87/1/115
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AT sahanamahesh identificationofmicroplasticsfromurbaninformalsolidwastelandfillsoilmpassociationswithcodandchloride