Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges

Hydrothermal carbonization (HTC) is considered as an efficient and constantly expanding eco-friendly methodology for thermochemical processing of high moisture waste biomass into solid biofuels and valuable carbonaceous materials. However, during HTC, a considerable amount of organics, initially pre...

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Main Authors: Antonio Picone, Maurizio Volpe, Antonio Messineo
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/10/2962
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author Antonio Picone
Maurizio Volpe
Antonio Messineo
author_facet Antonio Picone
Maurizio Volpe
Antonio Messineo
author_sort Antonio Picone
collection DOAJ
description Hydrothermal carbonization (HTC) is considered as an efficient and constantly expanding eco-friendly methodology for thermochemical processing of high moisture waste biomass into solid biofuels and valuable carbonaceous materials. However, during HTC, a considerable amount of organics, initially present in the feedstock, are found in the process water (PW). PW recirculation is attracting an increasing interest in the hydrothermal process field as it offers the potential to increase the carbon recovery yield while increasing hydrochar energy density. PW recirculation can be considered as a viable method for the valorization and reuse of the HTC aqueous phase, both by reducing the amount of additional water used for the process and maximizing energy recovery from the HTC liquid residual fraction. In this work, the effects of PW recirculation, for different starting waste biomasses, on the properties of hydrochars and liquid phase products are reviewed. The mechanism of production and evolution of hydrochar during recirculation steps are discussed, highlighting the possible pathways which could enhance energy and carbon recovery. Challenges of PW recirculation are presented and research opportunities proposed, showing how PW recirculation could increase the economic viability of the process while contributing in mitigating environmental impacts.
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spelling doaj.art-53478ff95fb443cebbe08fc9a7f3d6d42023-11-21T20:35:44ZengMDPI AGEnergies1996-10732021-05-011410296210.3390/en14102962Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and ChallengesAntonio Picone0Maurizio Volpe1Antonio Messineo2Faculty of Engineering and Architecture, University of Enna KORE, 94100 Enna, ItalyFaculty of Engineering and Architecture, University of Enna KORE, 94100 Enna, ItalyFaculty of Engineering and Architecture, University of Enna KORE, 94100 Enna, ItalyHydrothermal carbonization (HTC) is considered as an efficient and constantly expanding eco-friendly methodology for thermochemical processing of high moisture waste biomass into solid biofuels and valuable carbonaceous materials. However, during HTC, a considerable amount of organics, initially present in the feedstock, are found in the process water (PW). PW recirculation is attracting an increasing interest in the hydrothermal process field as it offers the potential to increase the carbon recovery yield while increasing hydrochar energy density. PW recirculation can be considered as a viable method for the valorization and reuse of the HTC aqueous phase, both by reducing the amount of additional water used for the process and maximizing energy recovery from the HTC liquid residual fraction. In this work, the effects of PW recirculation, for different starting waste biomasses, on the properties of hydrochars and liquid phase products are reviewed. The mechanism of production and evolution of hydrochar during recirculation steps are discussed, highlighting the possible pathways which could enhance energy and carbon recovery. Challenges of PW recirculation are presented and research opportunities proposed, showing how PW recirculation could increase the economic viability of the process while contributing in mitigating environmental impacts.https://www.mdpi.com/1996-1073/14/10/2962waste biomasshydrothermal carbonizationhydrocharprocess water recirculationenergy recovery
spellingShingle Antonio Picone
Maurizio Volpe
Antonio Messineo
Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
Energies
waste biomass
hydrothermal carbonization
hydrochar
process water recirculation
energy recovery
title Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
title_full Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
title_fullStr Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
title_full_unstemmed Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
title_short Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges
title_sort process water recirculation during hydrothermal carbonization of waste biomass current knowledge and challenges
topic waste biomass
hydrothermal carbonization
hydrochar
process water recirculation
energy recovery
url https://www.mdpi.com/1996-1073/14/10/2962
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