catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate]
The asymmetric unit of the title complex, {[Mn(C20H10Br2N3O5)(H2O)]·(CH3)2NCHO}n, consists of one MnIII ion, one (E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidate ligand (Schiff base), one water molecule and an N,N-dimethylformamide molecule. The coord...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812008501 |
| _version_ | 1828438620071002112 |
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| author | Abeer Mohamed Farag Teoh Siang Guan Hasnah Osman Madhukar Hemamalini Hoong-Kun Fun |
| author_facet | Abeer Mohamed Farag Teoh Siang Guan Hasnah Osman Madhukar Hemamalini Hoong-Kun Fun |
| author_sort | Abeer Mohamed Farag |
| collection | DOAJ |
| description | The asymmetric unit of the title complex, {[Mn(C20H10Br2N3O5)(H2O)]·(CH3)2NCHO}n, consists of one MnIII ion, one (E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidate ligand (Schiff base), one water molecule and an N,N-dimethylformamide molecule. The coordination geometry around the MnIII ion is a distorted octahedron, being surrounded by two O and two N atoms from the Schiff base, which are positioned in the equatorial plane. The water molecule and the O atom of the carbonyl group from the adjacent MnIII complex are situated at the axial positions, leading to a polymeric chain along the c axis. In the crystal, the complex and N,N-dimethylformamide molecules are connected via O—H...O, C—H...O and C—H...Br hydrogen bonds, forming a three-dimensional network. |
| first_indexed | 2024-12-10T20:07:23Z |
| format | Article |
| id | doaj.art-5350fc1e90a34f0cadffc3a88416435d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:07:23Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-5350fc1e90a34f0cadffc3a88416435d2022-12-22T01:35:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m365m36610.1107/S1600536812008501catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate]Abeer Mohamed FaragTeoh Siang GuanHasnah OsmanMadhukar HemamaliniHoong-Kun FunThe asymmetric unit of the title complex, {[Mn(C20H10Br2N3O5)(H2O)]·(CH3)2NCHO}n, consists of one MnIII ion, one (E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidate ligand (Schiff base), one water molecule and an N,N-dimethylformamide molecule. The coordination geometry around the MnIII ion is a distorted octahedron, being surrounded by two O and two N atoms from the Schiff base, which are positioned in the equatorial plane. The water molecule and the O atom of the carbonyl group from the adjacent MnIII complex are situated at the axial positions, leading to a polymeric chain along the c axis. In the crystal, the complex and N,N-dimethylformamide molecules are connected via O—H...O, C—H...O and C—H...Br hydrogen bonds, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812008501 |
| spellingShingle | Abeer Mohamed Farag Teoh Siang Guan Hasnah Osman Madhukar Hemamalini Hoong-Kun Fun catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] Acta Crystallographica Section E |
| title | catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] |
| title_full | catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] |
| title_fullStr | catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] |
| title_full_unstemmed | catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] |
| title_short | catena-Poly[[[aquamanganese(III)]-μ-(E)-5-bromo-N-[2-(5-bromo-2-oxidobenzylideneamino)-4-nitrophenyl]-2-oxidobenzamidato] N,N-dimethylfomamide monosolvate] |
| title_sort | catena poly aquamanganese iii amp 956 e 5 bromo n 2 5 bromo 2 oxidobenzylideneamino 4 nitrophenyl 2 oxidobenzamidato n n dimethylfomamide monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812008501 |
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