[(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate
The title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The IrI atom of the cationic complex has a distorted squ...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-07-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431462200685X |
| _version_ | 1818503808337051648 |
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| author | Joshua Rushlow Andrei V. Astashkin Daniel R. Albert Edward Rajaseelan |
| author_facet | Joshua Rushlow Andrei V. Astashkin Daniel R. Albert Edward Rajaseelan |
| author_sort | Joshua Rushlow |
| collection | DOAJ |
| description | The title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tricyclohexylphosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units. |
| first_indexed | 2024-12-10T21:28:49Z |
| format | Article |
| id | doaj.art-5382d8dfa5244bacb2c30ab8d9b594ac |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-10T21:28:49Z |
| publishDate | 2022-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-5382d8dfa5244bacb2c30ab8d9b594ac2022-12-22T01:32:54ZengInternational Union of CrystallographyIUCrData2414-31462022-07-0177x22068510.1107/S241431462200685Xwm4168[(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvateJoshua Rushlow0Andrei V. Astashkin1Daniel R. Albert2Edward Rajaseelan3Department of Chemistry, Millersville University, Millersville, PA 17551, USADepartment of Chemistry and Biochemistry, The University of Arizona, Tuscon, AZ, 85716, USADepartment of Chemistry, Millersville University, Millersville, PA 17551, USADepartment of Chemistry, Millersville University, Millersville, PA 17551, USAThe title compound, [Ir(C8H12)(C6H11N3)(C18H33P)]BF4·CH2Cl2, a triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetrafluoridoborate counter-anion, crystallizes with one dichloromethane solvent molecule per formula unit. The IrI atom of the cationic complex has a distorted square-planar coordination environment, defined by a bidentate cycloocta-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a tricyclohexylphosphane ligand. The complex crystallizes in a C-centered monoclinic unit cell and has an unusually high number of eight formula units.http://scripts.iucr.org/cgi-bin/paper?S241431462200685Xcrystal structureiridiumn-heterocyclic carbenes |
| spellingShingle | Joshua Rushlow Andrei V. Astashkin Daniel R. Albert Edward Rajaseelan [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate IUCrData crystal structure iridium n-heterocyclic carbenes |
| title | [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate |
| title_full | [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate |
| title_fullStr | [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate |
| title_full_unstemmed | [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate |
| title_short | [(1,2,5,6-η)-Cycloocta-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-ylidene)(tricyclohexylphosphane-κP)iridium(I) tetrafluoridoborate dichloromethane monosolvate |
| title_sort | 1 2 5 6 η cycloocta 1 5 diene 4 isopropyl 1 methyl 1 2 4 triazol 5 ylidene tricyclohexylphosphane κp iridium i tetrafluoridoborate dichloromethane monosolvate |
| topic | crystal structure iridium n-heterocyclic carbenes |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431462200685X |
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