The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales

Lysevatten, a lake in southwest Sweden, has experienced both acidification and recent changes in the amount of lake-water organic carbon (TOC), both causing concern across Europe and North America. A range of paleolimnological tools – diatom-inferred pH, inferred lake-water TOC from visible-near-inf...

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Main Authors: P. Rosén, R. Bindler, T. Korsman, T. Mighall, K. Bishop
Format: Article
Language:English
Published: Copernicus Publications 2011-09-01
Series:Biogeosciences
Online Access:http://www.biogeosciences.net/8/2717/2011/bg-8-2717-2011.pdf
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author P. Rosén
R. Bindler
T. Korsman
T. Mighall
K. Bishop
author_facet P. Rosén
R. Bindler
T. Korsman
T. Mighall
K. Bishop
author_sort P. Rosén
collection DOAJ
description Lysevatten, a lake in southwest Sweden, has experienced both acidification and recent changes in the amount of lake-water organic carbon (TOC), both causing concern across Europe and North America. A range of paleolimnological tools – diatom-inferred pH, inferred lake-water TOC from visible-near-infrared spectroscopy (VNIRS), multi-element geochemistry and pollen analysis, combined with geochemical modeling were used to reconstruct the lake's chemistry and surroundings back to the most recent deglaciation 12 500 years ago. The results reveal that the recent anthropogenic impacts are similar in magnitude to the long-term variation driven by natural catchment changes and early agricultural land use occurring over centuries and millennia. The combined reconstruction of both lake-water TOC and lithogenic element delivery can explain the major changes in lake-water pH and modeled acid neutralizing capacity during the past 12 500 years. The results raise important questions regarding what precisely comprises "reference" conditions (i.e., free from human impacts) as defined in the European Water Framework Directive.
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spelling doaj.art-53969a0a86ab45ed97d270a00b5b9a412022-12-22T03:32:03ZengCopernicus PublicationsBiogeosciences1726-41701726-41892011-09-01892717272710.5194/bg-8-2717-2011The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scalesP. RosénR. BindlerT. KorsmanT. MighallK. BishopLysevatten, a lake in southwest Sweden, has experienced both acidification and recent changes in the amount of lake-water organic carbon (TOC), both causing concern across Europe and North America. A range of paleolimnological tools – diatom-inferred pH, inferred lake-water TOC from visible-near-infrared spectroscopy (VNIRS), multi-element geochemistry and pollen analysis, combined with geochemical modeling were used to reconstruct the lake's chemistry and surroundings back to the most recent deglaciation 12 500 years ago. The results reveal that the recent anthropogenic impacts are similar in magnitude to the long-term variation driven by natural catchment changes and early agricultural land use occurring over centuries and millennia. The combined reconstruction of both lake-water TOC and lithogenic element delivery can explain the major changes in lake-water pH and modeled acid neutralizing capacity during the past 12 500 years. The results raise important questions regarding what precisely comprises "reference" conditions (i.e., free from human impacts) as defined in the European Water Framework Directive.http://www.biogeosciences.net/8/2717/2011/bg-8-2717-2011.pdf
spellingShingle P. Rosén
R. Bindler
T. Korsman
T. Mighall
K. Bishop
The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
Biogeosciences
title The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
title_full The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
title_fullStr The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
title_full_unstemmed The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
title_short The complementary power of pH and lake-water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
title_sort complementary power of ph and lake water organic carbon reconstructions for discerning the influences on surface waters across decadal to millennial time scales
url http://www.biogeosciences.net/8/2717/2011/bg-8-2717-2011.pdf
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