Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore
In this research, a coated graphite electrode was constructed for determination of Mg2+ in pharmaceutical supplements. The designed sensor demonstrates an ideal Nernstian slope (30.1 mV. Decade-1) over a wide concentration range (1×10-6- 1×10-1 Mol L-1). The selectivity of the sensor was evaluated o...
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Format: | Article |
Language: | English |
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Iranian Chemical Science and Technologies Association
2019-09-01
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Series: | International Journal of New Chemistry |
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Online Access: | http://www.ijnc.ir/article_33456_5d65e7d564164b6871da0ceb65b492a6.pdf |
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author | Neda Hajizadeh |
author_facet | Neda Hajizadeh |
author_sort | Neda Hajizadeh |
collection | DOAJ |
description | In this research, a coated graphite electrode was constructed for determination of Mg2+ in pharmaceutical supplements. The designed sensor demonstrates an ideal Nernstian slope (30.1 mV. Decade-1) over a wide concentration range (1×10-6- 1×10-1 Mol L-1). The selectivity of the sensor was evaluated over 16 different cations by matched potential method and no serious interference was observed from them. The designed electrode could also be used in partially non aqueous mediums up to the presence of 20% of organic solvents without any tangible alteration in Nernstian slope and linearity domain. The response time and life span of the proposed electrode were 20s and 2 months respectively. The function of the electrode was inspected in solutions with different pH value and also as an indicator electrode in potentiometric titration with EDTA. |
first_indexed | 2024-12-10T22:29:01Z |
format | Article |
id | doaj.art-53a22ed388fc49988e6738a5d93b83ff |
institution | Directory Open Access Journal |
issn | 2645-7237 2383-188X |
language | English |
last_indexed | 2024-12-10T22:29:01Z |
publishDate | 2019-09-01 |
publisher | Iranian Chemical Science and Technologies Association |
record_format | Article |
series | International Journal of New Chemistry |
spelling | doaj.art-53a22ed388fc49988e6738a5d93b83ff2022-12-22T01:31:06ZengIranian Chemical Science and Technologies AssociationInternational Journal of New Chemistry2645-72372383-188X2019-09-016319821410.22034/ijnc.2018.3345633456Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an IonophoreNeda Hajizadeh0M. A. In Analytical chemistry, Technical assistant of Jestar Sanat Company, No.28, Gilan St, Tehran, Iran.In this research, a coated graphite electrode was constructed for determination of Mg2+ in pharmaceutical supplements. The designed sensor demonstrates an ideal Nernstian slope (30.1 mV. Decade-1) over a wide concentration range (1×10-6- 1×10-1 Mol L-1). The selectivity of the sensor was evaluated over 16 different cations by matched potential method and no serious interference was observed from them. The designed electrode could also be used in partially non aqueous mediums up to the presence of 20% of organic solvents without any tangible alteration in Nernstian slope and linearity domain. The response time and life span of the proposed electrode were 20s and 2 months respectively. The function of the electrode was inspected in solutions with different pH value and also as an indicator electrode in potentiometric titration with EDTA.http://www.ijnc.ir/article_33456_5d65e7d564164b6871da0ceb65b492a6.pdfمنیزیومپتانسیومتریالکترود یون گزینریسپریدون |
spellingShingle | Neda Hajizadeh Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore International Journal of New Chemistry منیزیوم پتانسیومتری الکترود یون گزین ریسپریدون |
title | Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore |
title_full | Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore |
title_fullStr | Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore |
title_full_unstemmed | Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore |
title_short | Determination of Magnesium (II) by a Coated Graphite Electrode Based on Risperidone as an Ionophore |
title_sort | determination of magnesium ii by a coated graphite electrode based on risperidone as an ionophore |
topic | منیزیوم پتانسیومتری الکترود یون گزین ریسپریدون |
url | http://www.ijnc.ir/article_33456_5d65e7d564164b6871da0ceb65b492a6.pdf |
work_keys_str_mv | AT nedahajizadeh determinationofmagnesiumiibyacoatedgraphiteelectrodebasedonrisperidoneasanionophore |