Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate
The title compound, C22H25NO5, was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H...O and reinforcing C—H...O hydrogen bon...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017003607 |
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| author | Alejandro Manchado Mateo M. Salgado Álvaro Vicente David Díez Francisca Sanz Narciso M. Garrido |
| author_facet | Alejandro Manchado Mateo M. Salgado Álvaro Vicente David Díez Francisca Sanz Narciso M. Garrido |
| author_sort | Alejandro Manchado |
| collection | DOAJ |
| description | The title compound, C22H25NO5, was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H...O and reinforcing C—H...O hydrogen bonds link the molecules into infinite [010] chains. Further C—H...O hydrogen bonds cross-link the chains in the c-axis direction. |
| first_indexed | 2024-12-13T10:47:18Z |
| format | Article |
| id | doaj.art-53a5b25e35734c84a1ba4b0f0de4babe |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:47:18Z |
| publishDate | 2017-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-53a5b25e35734c84a1ba4b0f0de4babe2022-12-21T23:50:04ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-04-0173450350610.1107/S2056989017003607hb7652Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoateAlejandro Manchado0Mateo M. Salgado1Álvaro Vicente2David Díez3Francisca Sanz4Narciso M. Garrido5Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainDepartamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainDepartamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainDepartamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainServicio de Difracción de Rayos X, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainDepartamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caidos, 37008-Salamanca, SpainThe title compound, C22H25NO5, was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C—N—C(=O)—C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N—H...O and reinforcing C—H...O hydrogen bonds link the molecules into infinite [010] chains. Further C—H...O hydrogen bonds cross-link the chains in the c-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2056989017003607crystal structurehydrogen bondsCAN oxidationβ-lactameglutarate |
| spellingShingle | Alejandro Manchado Mateo M. Salgado Álvaro Vicente David Díez Francisca Sanz Narciso M. Garrido Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen bonds CAN oxidation β-lactame glutarate |
| title | Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate |
| title_full | Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate |
| title_fullStr | Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate |
| title_full_unstemmed | Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate |
| title_short | Crystal structure of methyl (4R)-4-(4-methoxybenzoyl)-4-{[(1R)-1-phenylethyl]carbamoyl}butanoate |
| title_sort | crystal structure of methyl 4r 4 4 methoxybenzoyl 4 1r 1 phenylethyl carbamoyl butanoate |
| topic | crystal structure hydrogen bonds CAN oxidation β-lactame glutarate |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017003607 |
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