Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach
The results are presented of a series of investigations concerning the application of the molecular-statistical approach to the calculation of thermodynamic quantities for the adsorption of molecules in the Henry region on adsorbent surfaces possessing certain surface symmetry properties, and in par...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1992-06-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361749200900201 |
| _version_ | 1797283526466338816 |
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| author | E.V. Aksenenko Yu. I. Tarasevich |
| author_facet | E.V. Aksenenko Yu. I. Tarasevich |
| author_sort | E.V. Aksenenko |
| collection | DOAJ |
| description | The results are presented of a series of investigations concerning the application of the molecular-statistical approach to the calculation of thermodynamic quantities for the adsorption of molecules in the Henry region on adsorbent surfaces possessing certain surface symmetry properties, and in particular for systems characterized by dispersion and polarization attraction and short-range atom-atom repulsion. Computational methods have been developed and the results for particular adsorption systems are presented with emphasis on the adsorption properties of layer silicates. Good correspondence between the calculated results and chromatographic data for a number of adsorbents strongly supports the view that the combination of chromatographic and molecular-statistical methods provides a powerful tool for the investigation of the structural and adsorption-selective characteristics of surface-porous adsorbents. |
| first_indexed | 2024-03-07T17:33:00Z |
| format | Article |
| id | doaj.art-53a76e7417c94cd49e377cc88344893f |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:33:00Z |
| publishDate | 1992-06-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-53a76e7417c94cd49e377cc88344893f2024-03-02T17:31:48ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381992-06-01910.1177/026361749200900201Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic ApproachE.V. AksenenkoYu. I. TarasevichThe results are presented of a series of investigations concerning the application of the molecular-statistical approach to the calculation of thermodynamic quantities for the adsorption of molecules in the Henry region on adsorbent surfaces possessing certain surface symmetry properties, and in particular for systems characterized by dispersion and polarization attraction and short-range atom-atom repulsion. Computational methods have been developed and the results for particular adsorption systems are presented with emphasis on the adsorption properties of layer silicates. Good correspondence between the calculated results and chromatographic data for a number of adsorbents strongly supports the view that the combination of chromatographic and molecular-statistical methods provides a powerful tool for the investigation of the structural and adsorption-selective characteristics of surface-porous adsorbents.https://doi.org/10.1177/026361749200900201 |
| spellingShingle | E.V. Aksenenko Yu. I. Tarasevich Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach Adsorption Science & Technology |
| title | Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach |
| title_full | Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach |
| title_fullStr | Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach |
| title_full_unstemmed | Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach |
| title_short | Non-Specific Adsorption of Hydrocarbons on Microporous Surfaces: A Comprehensive Molecular-Statistical/Chromatographic Approach |
| title_sort | non specific adsorption of hydrocarbons on microporous surfaces a comprehensive molecular statistical chromatographic approach |
| url | https://doi.org/10.1177/026361749200900201 |
| work_keys_str_mv | AT evaksenenko nonspecificadsorptionofhydrocarbonsonmicroporoussurfacesacomprehensivemolecularstatisticalchromatographicapproach AT yuitarasevich nonspecificadsorptionofhydrocarbonsonmicroporoussurfacesacomprehensivemolecularstatisticalchromatographicapproach |