Summary: | High chromium cast irons are commonly used as casting infiltration layers in the applications of wear resistance. The formation mechanism of the casting infiltration layer is essential to better develop the surface wear resistance materials using the casting infiltration method. In the present work, casting infiltration layers with various Cr contents were fabricated in situ on the surface of parent ZG45 steel. CALPHAD-type calculations using Thermo-Calc software, SEM, EDS and microhardness tests were performed to study the effect of Cr on the microstructure and hardness of casting infiltration layers. All the microstructures of casting infiltration layers were composed of pearlite matrix and eutectic M<sub>7</sub>C<sub>3</sub> carbide. With the increase in Cr content from 7.01 wt.% to 17.20 wt.%, the amount of M<sub>7</sub>C<sub>3</sub> carbide increased from 5.05 vol.% to 13.12 vol.%, resulting in the increment of microhardness. With the aid of simulations, the solidification behavior and formation mechanism of casting infiltration layers were revealed.
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