Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive

In this work, composite coatings of Cu/AlO(OH) were produced by electrodeposition on steel substrates using a pyrophosphate-based bath containing allyl alcohol as an additive. The electrodeposition of the composite coatings was carried out using a 23 central composite design (CCD), aiming to verify...

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Main Authors: Thaís Guimarães de Lima Rezende, Dalva Cristina Baptista do Lago, Deborah Vargas Cesar, Lilian Ferreira de Senna
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2017-09-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/pdf/mr/v20s2/1516-1439-mr-1980-5373-MR-2016-0995.pdf
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author Thaís Guimarães de Lima Rezende
Dalva Cristina Baptista do Lago
Deborah Vargas Cesar
Lilian Ferreira de Senna
author_facet Thaís Guimarães de Lima Rezende
Dalva Cristina Baptista do Lago
Deborah Vargas Cesar
Lilian Ferreira de Senna
author_sort Thaís Guimarães de Lima Rezende
collection DOAJ
description In this work, composite coatings of Cu/AlO(OH) were produced by electrodeposition on steel substrates using a pyrophosphate-based bath containing allyl alcohol as an additive. The electrodeposition of the composite coatings was carried out using a 23 central composite design (CCD), aiming to verify the effects of the deposition parameters (previous stirring time (t), the stirring speed (S) and the current density (j)), considered the entry variables, on the electrochemical behavior of Cu/AlO(OH) coating, the response variables of the CCD. The results indicated that a decrease of the parameters j and S directly influenced the values of Rp and Rct, leading to the production of protective coatings. The best result (Rp = 211 Ω and Rct = 221 Ω) was obtained under conditions where t = 120 min, S = 1300 rpm and j = 7 A m-2. Dispersed bohemite particles could be noted on the surface of the composite coating.
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spelling doaj.art-5417e584d9a44b4fa98f4e511f26b05b2022-12-22T04:15:31ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392017-09-0120suppl 237438510.1590/1980-5373-mr-2016-0995Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an AdditiveThaís Guimarães de Lima RezendeDalva Cristina Baptista do LagoDeborah Vargas CesarLilian Ferreira de SennaIn this work, composite coatings of Cu/AlO(OH) were produced by electrodeposition on steel substrates using a pyrophosphate-based bath containing allyl alcohol as an additive. The electrodeposition of the composite coatings was carried out using a 23 central composite design (CCD), aiming to verify the effects of the deposition parameters (previous stirring time (t), the stirring speed (S) and the current density (j)), considered the entry variables, on the electrochemical behavior of Cu/AlO(OH) coating, the response variables of the CCD. The results indicated that a decrease of the parameters j and S directly influenced the values of Rp and Rct, leading to the production of protective coatings. The best result (Rp = 211 Ω and Rct = 221 Ω) was obtained under conditions where t = 120 min, S = 1300 rpm and j = 7 A m-2. Dispersed bohemite particles could be noted on the surface of the composite coating.http://www.scielo.br/pdf/mr/v20s2/1516-1439-mr-1980-5373-MR-2016-0995.pdfElectrochemical co-deposition processCu/AlO(OH)Composite coatingsBoehmiteAdditiveAllyl alcohol
spellingShingle Thaís Guimarães de Lima Rezende
Dalva Cristina Baptista do Lago
Deborah Vargas Cesar
Lilian Ferreira de Senna
Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
Materials Research
Electrochemical co-deposition process
Cu/AlO(OH)
Composite coatings
Boehmite
Additive
Allyl alcohol
title Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
title_full Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
title_fullStr Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
title_full_unstemmed Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
title_short Electrodeposition of Composite Coatings of Cu/AlO(OH) Using Allyl Alcohol as an Additive
title_sort electrodeposition of composite coatings of cu alo oh using allyl alcohol as an additive
topic Electrochemical co-deposition process
Cu/AlO(OH)
Composite coatings
Boehmite
Additive
Allyl alcohol
url http://www.scielo.br/pdf/mr/v20s2/1516-1439-mr-1980-5373-MR-2016-0995.pdf
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