Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake
We report on a two-step catalytic process, where deoiled seed cake as a feed was rapidly depolymerized and converted to a chemical intermediate under mild conditions, and a polymer compound was subsequently synthesized in the presence of an initiator under microwave irradiation. 5-Hydroxymethylfurfu...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Elsevier
2017-09-01
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| Series: | Journal of Science: Advanced Materials and Devices |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468217917300461 |
| _version_ | 1818293050342899712 |
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| author | B.S. Surendra M. Veerabhadraswamy |
| author_facet | B.S. Surendra M. Veerabhadraswamy |
| author_sort | B.S. Surendra |
| collection | DOAJ |
| description | We report on a two-step catalytic process, where deoiled seed cake as a feed was rapidly depolymerized and converted to a chemical intermediate under mild conditions, and a polymer compound was subsequently synthesized in the presence of an initiator under microwave irradiation. 5-Hydroxymethylfurfural (5-HMF) is a significant chemical intermediate compound synthesized from a deoiled Jatropha seed cake under microwave irradiation in the presence of a heterogeneous acid activated Bentonite catalyst. This compound is suitable for the synthesis of polymers. Our study reveals that the synthesis process is an energy-efficient and cost-effective conversion of the deoiled seed cake into the polymer compound through the bioplatform chemical intermediate. The synthesized material was well characterized, confirming the formation and structures of the prepared catalysts. |
| first_indexed | 2024-12-13T03:09:41Z |
| format | Article |
| id | doaj.art-546ba258035944849275690b4dab2c3b |
| institution | Directory Open Access Journal |
| issn | 2468-2179 |
| language | English |
| last_indexed | 2024-12-13T03:09:41Z |
| publishDate | 2017-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Science: Advanced Materials and Devices |
| spelling | doaj.art-546ba258035944849275690b4dab2c3b2022-12-22T00:01:38ZengElsevierJournal of Science: Advanced Materials and Devices2468-21792017-09-012334034610.1016/j.jsamd.2017.07.004Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cakeB.S. Surendra0M. Veerabhadraswamy1East West Institute of Technology, Dept. of Chemistry, Bangalore 560091, IndiaGreen Chemistry Center, P E S University, BSK III Stage, Bengalure 56085, IndiaWe report on a two-step catalytic process, where deoiled seed cake as a feed was rapidly depolymerized and converted to a chemical intermediate under mild conditions, and a polymer compound was subsequently synthesized in the presence of an initiator under microwave irradiation. 5-Hydroxymethylfurfural (5-HMF) is a significant chemical intermediate compound synthesized from a deoiled Jatropha seed cake under microwave irradiation in the presence of a heterogeneous acid activated Bentonite catalyst. This compound is suitable for the synthesis of polymers. Our study reveals that the synthesis process is an energy-efficient and cost-effective conversion of the deoiled seed cake into the polymer compound through the bioplatform chemical intermediate. The synthesized material was well characterized, confirming the formation and structures of the prepared catalysts.http://www.sciencedirect.com/science/article/pii/S24682179173004615-HMFDeoiled seed cakeAcid activated clayMicrowave irradiationPolymer |
| spellingShingle | B.S. Surendra M. Veerabhadraswamy Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake Journal of Science: Advanced Materials and Devices 5-HMF Deoiled seed cake Acid activated clay Microwave irradiation Polymer |
| title | Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake |
| title_full | Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake |
| title_fullStr | Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake |
| title_full_unstemmed | Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake |
| title_short | Microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from Jatropha deoiled seed cake |
| title_sort | microwave assisted synthesis of polymer via bioplatform chemical intermediate derived from jatropha deoiled seed cake |
| topic | 5-HMF Deoiled seed cake Acid activated clay Microwave irradiation Polymer |
| url | http://www.sciencedirect.com/science/article/pii/S2468217917300461 |
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