Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions

A hydrothermal interaction of oceanic rocks with seawater was simulated in the Selektor program at 350°C and 25 MPa. It was found that the maximum extraction of major ore-forming elements of massive sulfide deposits from basalts occurs under reducing conditions: 2.9 Ч 10-3 mol Fe at ξ = -lg(rock/sea...

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Main Author: G. A. Tret'yakov
Format: Article
Language:English
Published: A.N. Zavaritsky Institute of Geology and Geochemistry 2015-12-01
Series:Литосфера
Subjects:
Online Access:https://www.lithosphere.ru/jour/article/view/166
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author G. A. Tret'yakov
author_facet G. A. Tret'yakov
author_sort G. A. Tret'yakov
collection DOAJ
description A hydrothermal interaction of oceanic rocks with seawater was simulated in the Selektor program at 350°C and 25 MPa. It was found that the maximum extraction of major ore-forming elements of massive sulfide deposits from basalts occurs under reducing conditions: 2.9 Ч 10-3 mol Fe at ξ = -lg(rock/seawater) of 2.1, 3.3 Ч Ч 10-4 mol Zn at ξ = 0.625 and 5.02 Ч 10-5 mol Cu at ξ = 1.4. The major transport complexes of these elements in hydrothermal fluids are FeCl20 > FeCl+ > Fe2+, ZnCl+ > ZnCl20 > ZnCl3-, CuCl32- > CuCl2-. According to recycling model, the mafic rocks (gabbro, basalts) are the most likely source of metals for hydrothermal sulfide systems.
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spelling doaj.art-5476a213e1234ced8986afaa11191d1a2022-12-22T00:52:46ZengA.N. Zavaritsky Institute of Geology and GeochemistryЛитосфера1681-90042500-302X2015-12-0106142147166Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditionsG. A. Tret'yakov0Institute of Mineralogy UB RASA hydrothermal interaction of oceanic rocks with seawater was simulated in the Selektor program at 350°C and 25 MPa. It was found that the maximum extraction of major ore-forming elements of massive sulfide deposits from basalts occurs under reducing conditions: 2.9 Ч 10-3 mol Fe at ξ = -lg(rock/seawater) of 2.1, 3.3 Ч Ч 10-4 mol Zn at ξ = 0.625 and 5.02 Ч 10-5 mol Cu at ξ = 1.4. The major transport complexes of these elements in hydrothermal fluids are FeCl20 > FeCl+ > Fe2+, ZnCl+ > ZnCl20 > ZnCl3-, CuCl32- > CuCl2-. According to recycling model, the mafic rocks (gabbro, basalts) are the most likely source of metals for hydrothermal sulfide systems.https://www.lithosphere.ru/jour/article/view/166физико-химическое моделированиевзаимодействие морской воды с породамиминеральная ассоциациячерный курильщикэкстракция элементовphysico-chemical modelingrock-seawater interactionmineral assemblageblack smokerextraction of elements
spellingShingle G. A. Tret'yakov
Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
Литосфера
физико-химическое моделирование
взаимодействие морской воды с породами
минеральная ассоциация
черный курильщик
экстракция элементов
physico-chemical modeling
rock-seawater interaction
mineral assemblage
black smoker
extraction of elements
title Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
title_full Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
title_fullStr Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
title_full_unstemmed Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
title_short Mineral assemblages and behavior of ore-forming elements at rock-seawater interaction in hydrothermal conditions
title_sort mineral assemblages and behavior of ore forming elements at rock seawater interaction in hydrothermal conditions
topic физико-химическое моделирование
взаимодействие морской воды с породами
минеральная ассоциация
черный курильщик
экстракция элементов
physico-chemical modeling
rock-seawater interaction
mineral assemblage
black smoker
extraction of elements
url https://www.lithosphere.ru/jour/article/view/166
work_keys_str_mv AT gatretyakov mineralassemblagesandbehavioroforeformingelementsatrockseawaterinteractioninhydrothermalconditions