Palladium-catalyzed cross-couplings in the synthesis of agrochemicals
Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig am...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
KeAi Communications Co., Ltd.
2022-12-01
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| Series: | Advanced Agrochem |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2773237122000259 |
| _version_ | 1827302687833587712 |
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| author | Yuxin Zhu Wenfeng Dong Wenjun Tang |
| author_facet | Yuxin Zhu Wenfeng Dong Wenjun Tang |
| author_sort | Yuxin Zhu |
| collection | DOAJ |
| description | Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed. |
| first_indexed | 2024-04-24T16:48:18Z |
| format | Article |
| id | doaj.art-5476b441874e43d48bdefb008d3b5aac |
| institution | Directory Open Access Journal |
| issn | 2773-2371 |
| language | English |
| last_indexed | 2024-04-24T16:48:18Z |
| publishDate | 2022-12-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Advanced Agrochem |
| spelling | doaj.art-5476b441874e43d48bdefb008d3b5aac2024-03-29T05:51:35ZengKeAi Communications Co., Ltd.Advanced Agrochem2773-23712022-12-0112125138Palladium-catalyzed cross-couplings in the synthesis of agrochemicalsYuxin Zhu0Wenfeng Dong1Wenjun Tang2State Key Laboratory of Bio-Organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, ChinaSchool of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou, 310024, ChinaState Key Laboratory of Bio-Organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China; School of Chemistry and Materials Science, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, 1 Sub-lane Xiangshan, Hangzhou, 310024, China; Corresponding author. State Key Laboratory of Bio-Organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032, China.Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed.http://www.sciencedirect.com/science/article/pii/S2773237122000259 |
| spellingShingle | Yuxin Zhu Wenfeng Dong Wenjun Tang Palladium-catalyzed cross-couplings in the synthesis of agrochemicals Advanced Agrochem |
| title | Palladium-catalyzed cross-couplings in the synthesis of agrochemicals |
| title_full | Palladium-catalyzed cross-couplings in the synthesis of agrochemicals |
| title_fullStr | Palladium-catalyzed cross-couplings in the synthesis of agrochemicals |
| title_full_unstemmed | Palladium-catalyzed cross-couplings in the synthesis of agrochemicals |
| title_short | Palladium-catalyzed cross-couplings in the synthesis of agrochemicals |
| title_sort | palladium catalyzed cross couplings in the synthesis of agrochemicals |
| url | http://www.sciencedirect.com/science/article/pii/S2773237122000259 |
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