11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one
In the title compound, C34H26F2N2O2S, an intramolecular O—H...N hydrogen bond forms an S(5) ring motif. The piperidine ring adopts a chair conformation. The thiazolidine ring and one of the pyrrolidine rings adopt envolope conformations with methylene C atoms at the flap, whereas the o...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812025512 |
| _version_ | 1818960745085272064 |
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| author | Raju Suresh Kumar Hasnah Osman Abdulrahman I. Almansour Suhana Arshad Ibrahim Abdul Razak |
| author_facet | Raju Suresh Kumar Hasnah Osman Abdulrahman I. Almansour Suhana Arshad Ibrahim Abdul Razak |
| author_sort | Raju Suresh Kumar |
| collection | DOAJ |
| description | In the title compound, C34H26F2N2O2S, an intramolecular O—H...N hydrogen bond forms an S(5) ring motif. The piperidine ring adopts a chair conformation. The thiazolidine ring and one of the pyrrolidine rings adopt envolope conformations with methylene C atoms at the flap, whereas the other pyrrolidine ring adopts a half-chair conformation. The fluoro-substituted benzene rings form dihedral angles of 32.25 (10) and 38.27 (10)°, respectively, with the mean plane of the dihydroacenaphthylene ring system [maximum deviation = 0.043 (2) Å]. The dihedral angle between the fluoro-substituted benzene rings is 64.13 (14)°. In the crystal, molecules are linked by weak C—H...O, C—H...F and C—H...S hydrogen bonds into a three-dimensional network. |
| first_indexed | 2024-12-20T12:02:25Z |
| format | Article |
| id | doaj.art-547af2c540d94f6eb30a4d56f6bbe160 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T12:02:25Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-547af2c540d94f6eb30a4d56f6bbe1602022-12-21T19:41:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2094o209510.1107/S160053681202551211-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-oneRaju Suresh KumarHasnah OsmanAbdulrahman I. AlmansourSuhana ArshadIbrahim Abdul RazakIn the title compound, C34H26F2N2O2S, an intramolecular O—H...N hydrogen bond forms an S(5) ring motif. The piperidine ring adopts a chair conformation. The thiazolidine ring and one of the pyrrolidine rings adopt envolope conformations with methylene C atoms at the flap, whereas the other pyrrolidine ring adopts a half-chair conformation. The fluoro-substituted benzene rings form dihedral angles of 32.25 (10) and 38.27 (10)°, respectively, with the mean plane of the dihydroacenaphthylene ring system [maximum deviation = 0.043 (2) Å]. The dihedral angle between the fluoro-substituted benzene rings is 64.13 (14)°. In the crystal, molecules are linked by weak C—H...O, C—H...F and C—H...S hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536812025512 |
| spellingShingle | Raju Suresh Kumar Hasnah Osman Abdulrahman I. Almansour Suhana Arshad Ibrahim Abdul Razak 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one Acta Crystallographica Section E |
| title | 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_full | 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_fullStr | 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_full_unstemmed | 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_short | 11-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-14-hydroxy-6-thia-3,13-diazaheptacyclo[13.7.1.19,13.02,9.02,14.03,7.019,23]tetracosa-1(22),15(23),16,18,20-pentaen-10-one |
| title_sort | 11 e 2 fluorobenzylidene 8 2 fluorophenyl 14 hydroxy 6 thia 3 13 diazaheptacyclo 13 7 1 19 13 02 9 02 14 03 7 019 23 tetracosa 1 22 15 23 16 18 20 pentaen 10 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812025512 |
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