Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review

Metal oxide semiconductor gas sensors are widely used to detect toxic and inflammable gases in industrial production and daily life. The main research hotspot in this field is the synthesis of gas sensing materials. Previous studies have shown that incorporating two or more metal oxides to form a he...

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Main Authors: Fan-Jian Meng, Rui-Feng Xin, Shan-Xin Li
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/1/263
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author Fan-Jian Meng
Rui-Feng Xin
Shan-Xin Li
author_facet Fan-Jian Meng
Rui-Feng Xin
Shan-Xin Li
author_sort Fan-Jian Meng
collection DOAJ
description Metal oxide semiconductor gas sensors are widely used to detect toxic and inflammable gases in industrial production and daily life. The main research hotspot in this field is the synthesis of gas sensing materials. Previous studies have shown that incorporating two or more metal oxides to form a heterojunction interface can exhibit superior gas sensing performance in response and selectivity compared with single phase. This review focuses on mainly the synthesis methods and gas sensing mechanisms of metal oxide heterostructures. A significant number of heterostructures with different morphologies and shapes have been fabricated, which exhibit specific sensing performance toward a specific target gas. Among these synthesis methods, the hydrothermal method is noteworthy due to the fabrication of diverse structures, such as nanorod-like, nanoflower-like, and hollow sphere structures with enhanced sensing properties. In addition, it should be noted that the combination of different synthesis methods is also an efficient way to obtain metal oxide heterostructures with novel morphologies. Despite advanced methods in the metal oxide semiconductors and nanotechnology field, there are still some new issues which deserve further investigation, such as long-term chemical stability of sensing materials, reproducibility of the fabrication process, and selectivity toward homogeneous gases. Moreover, the gas sensing mechanism of metal oxide heterostructures is controversial. It should be clarified so as to further integrate laboratory theory research with practical exploitation.
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spelling doaj.art-547bedb76f0e4dff9b6a46c06d9c968f2023-11-16T15:49:17ZengMDPI AGMaterials1996-19442022-12-0116126310.3390/ma16010263Metal Oxide Heterostructures for Improving Gas Sensing Properties: A ReviewFan-Jian Meng0Rui-Feng Xin1Shan-Xin Li2State Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, ChinaState Key Laboratory of Advanced Metallurgy, School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, ChinaSchool of Materials, Sun Yat-sen University, Shenzhen 518107, ChinaMetal oxide semiconductor gas sensors are widely used to detect toxic and inflammable gases in industrial production and daily life. The main research hotspot in this field is the synthesis of gas sensing materials. Previous studies have shown that incorporating two or more metal oxides to form a heterojunction interface can exhibit superior gas sensing performance in response and selectivity compared with single phase. This review focuses on mainly the synthesis methods and gas sensing mechanisms of metal oxide heterostructures. A significant number of heterostructures with different morphologies and shapes have been fabricated, which exhibit specific sensing performance toward a specific target gas. Among these synthesis methods, the hydrothermal method is noteworthy due to the fabrication of diverse structures, such as nanorod-like, nanoflower-like, and hollow sphere structures with enhanced sensing properties. In addition, it should be noted that the combination of different synthesis methods is also an efficient way to obtain metal oxide heterostructures with novel morphologies. Despite advanced methods in the metal oxide semiconductors and nanotechnology field, there are still some new issues which deserve further investigation, such as long-term chemical stability of sensing materials, reproducibility of the fabrication process, and selectivity toward homogeneous gases. Moreover, the gas sensing mechanism of metal oxide heterostructures is controversial. It should be clarified so as to further integrate laboratory theory research with practical exploitation.https://www.mdpi.com/1996-1944/16/1/263metal oxide semiconductorsensing materialsheterostructuressynthesis methodsgas sensing mechanism
spellingShingle Fan-Jian Meng
Rui-Feng Xin
Shan-Xin Li
Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
Materials
metal oxide semiconductor
sensing materials
heterostructures
synthesis methods
gas sensing mechanism
title Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
title_full Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
title_fullStr Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
title_full_unstemmed Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
title_short Metal Oxide Heterostructures for Improving Gas Sensing Properties: A Review
title_sort metal oxide heterostructures for improving gas sensing properties a review
topic metal oxide semiconductor
sensing materials
heterostructures
synthesis methods
gas sensing mechanism
url https://www.mdpi.com/1996-1944/16/1/263
work_keys_str_mv AT fanjianmeng metaloxideheterostructuresforimprovinggassensingpropertiesareview
AT ruifengxin metaloxideheterostructuresforimprovinggassensingpropertiesareview
AT shanxinli metaloxideheterostructuresforimprovinggassensingpropertiesareview