Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)]
In the polymeric title compound, [Cu3W2(CN)16(C7H6N2)6(H2O)]n, the coordination geometry of the W(V) atom is eight-coordinate dodecahedral, where four CN groups of [W(CN)8] are bridged to CuII ions, and the other four CN groups are not bridged. The coordination geometries of the CuII ions are five-c...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681000841X |
| _version_ | 1819280226438348800 |
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| author | Kenta Imoto Souhei Kaneko Yoshihide Tsunobuchi Koji Nakabayashi Shin-ichi Ohkoshi |
| author_facet | Kenta Imoto Souhei Kaneko Yoshihide Tsunobuchi Koji Nakabayashi Shin-ichi Ohkoshi |
| author_sort | Kenta Imoto |
| collection | DOAJ |
| description | In the polymeric title compound, [Cu3W2(CN)16(C7H6N2)6(H2O)]n, the coordination geometry of the W(V) atom is eight-coordinate dodecahedral, where four CN groups of [W(CN)8] are bridged to CuII ions, and the other four CN groups are not bridged. The coordination geometries of the CuII ions are five-coordinate pseudo-square-based pyramidal. There are two distinct Cu sites, which build and link the cyanido-bridged Cu—W ladder chains. Successive connections lead to the formation of a two-dimensional network. The H atoms of a coordinated water molecule and the imino groups form hydrogen bonds to the N atoms of non-bridged CN groups. |
| first_indexed | 2024-12-24T00:40:26Z |
| format | Article |
| id | doaj.art-54c6f7cbab7a4ac0bbb12036ddafffd3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:40:26Z |
| publishDate | 2010-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-54c6f7cbab7a4ac0bbb12036ddafffd32022-12-21T17:23:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-04-01664m403m40410.1107/S160053681000841XPoly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)]Kenta ImotoSouhei KanekoYoshihide TsunobuchiKoji NakabayashiShin-ichi OhkoshiIn the polymeric title compound, [Cu3W2(CN)16(C7H6N2)6(H2O)]n, the coordination geometry of the W(V) atom is eight-coordinate dodecahedral, where four CN groups of [W(CN)8] are bridged to CuII ions, and the other four CN groups are not bridged. The coordination geometries of the CuII ions are five-coordinate pseudo-square-based pyramidal. There are two distinct Cu sites, which build and link the cyanido-bridged Cu—W ladder chains. Successive connections lead to the formation of a two-dimensional network. The H atoms of a coordinated water molecule and the imino groups form hydrogen bonds to the N atoms of non-bridged CN groups.http://scripts.iucr.org/cgi-bin/paper?S160053681000841X |
| spellingShingle | Kenta Imoto Souhei Kaneko Yoshihide Tsunobuchi Koji Nakabayashi Shin-ichi Ohkoshi Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] Acta Crystallographica Section E |
| title | Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] |
| title_full | Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] |
| title_fullStr | Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] |
| title_full_unstemmed | Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] |
| title_short | Poly[aquahexabenzimidazoleocta-μ-cyanido-octacyanidotricopper(II)ditungstate(V)] |
| title_sort | poly aquahexabenzimidazoleocta amp 956 cyanido octacyanidotricopper ii ditungstate v |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681000841X |
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