Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys

Ternary alloys SnZn12Sb8, SnZn10Sb10, SnZn8Sb12, SnZn6Sb14, and SnZn2Sb18 were prepared by induction melting. Electrochemical behavior and wetting (contact angle) of prepared as-cast samples were investigated using open circuit potential measurement and sessile drop technique. The results of ele...

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Main Authors: Mladenović Srba A., Ivanić Ljubica S., Rajčić-Vujasinović Mirjana M., Ivanov Svetlana Lj., Gusković Dragoslav M.
Format: Article
Language:English
Published: Association of Chemical Engineers of Serbia 2013-01-01
Series:Hemijska Industrija
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0367-598X/2013/0367-598X1200084M.pdf
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author Mladenović Srba A.
Ivanić Ljubica S.
Rajčić-Vujasinović Mirjana M.
Ivanov Svetlana Lj.
Gusković Dragoslav M.
author_facet Mladenović Srba A.
Ivanić Ljubica S.
Rajčić-Vujasinović Mirjana M.
Ivanov Svetlana Lj.
Gusković Dragoslav M.
author_sort Mladenović Srba A.
collection DOAJ
description Ternary alloys SnZn12Sb8, SnZn10Sb10, SnZn8Sb12, SnZn6Sb14, and SnZn2Sb18 were prepared by induction melting. Electrochemical behavior and wetting (contact angle) of prepared as-cast samples were investigated using open circuit potential measurement and sessile drop technique. The results of electrochemical investigation show that open-circuit potential, few seconds after immersing of electrodes, shifts toward more negative values, indicating a relatively smaller rate of dissolution during the spontaneous dissolution process under the curentless conditions. After that period, the values of potential tend to be constant with time. It was found that all investigated alloys have poor wettability on copper substrate and the contact angle values decrease with increasing superheat temperature.
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spelling doaj.art-54e4721e278345908b0075fc05f38c832022-12-21T23:30:52ZengAssociation of Chemical Engineers of SerbiaHemijska Industrija0367-598X2013-01-0167347748410.2298/HEMIND120608084MElectrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloysMladenović Srba A.Ivanić Ljubica S.Rajčić-Vujasinović Mirjana M.Ivanov Svetlana Lj.Gusković Dragoslav M.Ternary alloys SnZn12Sb8, SnZn10Sb10, SnZn8Sb12, SnZn6Sb14, and SnZn2Sb18 were prepared by induction melting. Electrochemical behavior and wetting (contact angle) of prepared as-cast samples were investigated using open circuit potential measurement and sessile drop technique. The results of electrochemical investigation show that open-circuit potential, few seconds after immersing of electrodes, shifts toward more negative values, indicating a relatively smaller rate of dissolution during the spontaneous dissolution process under the curentless conditions. After that period, the values of potential tend to be constant with time. It was found that all investigated alloys have poor wettability on copper substrate and the contact angle values decrease with increasing superheat temperature.http://www.doiserbia.nb.rs/img/doi/0367-598X/2013/0367-598X1200084M.pdfopen-circuit potentialcontact anglestep soldering alloyssessile drop technique
spellingShingle Mladenović Srba A.
Ivanić Ljubica S.
Rajčić-Vujasinović Mirjana M.
Ivanov Svetlana Lj.
Gusković Dragoslav M.
Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
Hemijska Industrija
open-circuit potential
contact angle
step soldering alloys
sessile drop technique
title Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
title_full Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
title_fullStr Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
title_full_unstemmed Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
title_short Electrochemical and wetting behavior of as-cast Sn-Zn-Sb lead free solders alloys
title_sort electrochemical and wetting behavior of as cast sn zn sb lead free solders alloys
topic open-circuit potential
contact angle
step soldering alloys
sessile drop technique
url http://www.doiserbia.nb.rs/img/doi/0367-598X/2013/0367-598X1200084M.pdf
work_keys_str_mv AT mladenovicsrbaa electrochemicalandwettingbehaviorofascastsnznsbleadfreesoldersalloys
AT ivanicljubicas electrochemicalandwettingbehaviorofascastsnznsbleadfreesoldersalloys
AT rajcicvujasinovicmirjanam electrochemicalandwettingbehaviorofascastsnznsbleadfreesoldersalloys
AT ivanovsvetlanalj electrochemicalandwettingbehaviorofascastsnznsbleadfreesoldersalloys
AT guskovicdragoslavm electrochemicalandwettingbehaviorofascastsnznsbleadfreesoldersalloys