Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)]
In the title compound, [Co(C8H5NO4)(C12H12N2)]n, the CoII ion presents a distorted CoO4N2 octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the oth...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810030710 |
| _version_ | 1819280090519830528 |
|---|---|
| author | Shie Fu Lush Fwu Ming Shen |
| author_facet | Shie Fu Lush Fwu Ming Shen |
| author_sort | Shie Fu Lush |
| collection | DOAJ |
| description | In the title compound, [Co(C8H5NO4)(C12H12N2)]n, the CoII ion presents a distorted CoO4N2 octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the other carboxylate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis(4-pyridyl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis(4-pyridyl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H...O hydrogen bonding and N—H...π interactions are observed in the crystal structure. A void of 69 (5) Å3 is present in the crystal structure, but no solvent molecule can be located reasonably. |
| first_indexed | 2024-12-24T00:38:16Z |
| format | Article |
| id | doaj.art-54e87c6fee654bddafd09b4effde7c16 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:38:16Z |
| publishDate | 2010-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-54e87c6fee654bddafd09b4effde7c162022-12-21T17:24:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1069m107010.1107/S1600536810030710Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)]Shie Fu LushFwu Ming ShenIn the title compound, [Co(C8H5NO4)(C12H12N2)]n, the CoII ion presents a distorted CoO4N2 octahedral coordination geometry, formed by three 5-aminoisophthalate dianions and two 1,2-bis(4-pyridyl)ethane ligands. One carboxylate group of the 5-aminoisophthalate dianion chelates a Co cation and the other carboxylate group bridges the other two Co cations, while the terminal N atoms of the 1,2-bis(4-pyridyl)ethane ligand coordinate the neighboring Co cations, forming a two-dimensional polymeric architecture. Two pyridine rings of the 1,2-bis(4-pyridyl)ethane ligand are twisted to each other with a dihedral angle of 50.94 (16)°. Weak C—H...O hydrogen bonding and N—H...π interactions are observed in the crystal structure. A void of 69 (5) Å3 is present in the crystal structure, but no solvent molecule can be located reasonably.http://scripts.iucr.org/cgi-bin/paper?S1600536810030710 |
| spellingShingle | Shie Fu Lush Fwu Ming Shen Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] Acta Crystallographica Section E |
| title | Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] |
| title_full | Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] |
| title_fullStr | Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] |
| title_full_unstemmed | Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] |
| title_short | Poly[(μ3-5-aminoisophthalato-κ4O,O′:O′′:O′′′)[μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′]cobalt(II)] |
| title_sort | poly amp 956 3 5 aminoisophthalato amp 954 4o o amp 8242 o amp 8242 amp 8242 o amp 8242 amp 8242 amp 8242 amp 956 2 1 2 bis 4 pyridyl ethane amp 954 2n n amp 8242 cobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810030710 |
| work_keys_str_mv | AT shiefulush polyamp95635aminoisophthalatoamp9544ooamp8242oamp8242amp8242oamp8242amp8242amp8242amp956212bis4pyridylethaneamp9542nnamp8242cobaltii AT fwumingshen polyamp95635aminoisophthalatoamp9544ooamp8242oamp8242amp8242oamp8242amp8242amp8242amp956212bis4pyridylethaneamp9542nnamp8242cobaltii |