Bonding of PMMA to silicon by femtosecond laser pulses

Abstract Many devices and objects, from microelectronics to microfluidics, consist of parts made from dissimilar materials, such as different polymers, metals or semiconductors. Techniques for joining such hybrid micro-devices, generally, are based on gluing or thermal processes, which all present s...

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Main Authors: Filippo Maria Conte Capodacqua, Annalisa Volpe, Caterina Gaudiuso, Antonio Ancona
Format: Article
Language:English
Published: Nature Portfolio 2023-03-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-023-31969-y
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author Filippo Maria Conte Capodacqua
Annalisa Volpe
Caterina Gaudiuso
Antonio Ancona
author_facet Filippo Maria Conte Capodacqua
Annalisa Volpe
Caterina Gaudiuso
Antonio Ancona
author_sort Filippo Maria Conte Capodacqua
collection DOAJ
description Abstract Many devices and objects, from microelectronics to microfluidics, consist of parts made from dissimilar materials, such as different polymers, metals or semiconductors. Techniques for joining such hybrid micro-devices, generally, are based on gluing or thermal processes, which all present some drawbacks. For example, these methods are unable to control the size and shape of the bonded area, and present risks of deterioration and contamination of the substrates. Ultrashort laser bonding is a non-contact and flexible technique to precisely join similar and dissimilar materials, used both for joining polymers, and polymers to metallic substrates, but not yet for joining polymers to silicon. We report on direct transmission femtosecond laser bonding of poly(methyl methacrylate) (PMMA) and silicon. The laser process was performed by focusing ultrashort laser pulses at high repetition rate at the interface between the two materials through the PMMA upper layer. The PMMA-Si bond strength was evaluated as a function of different laser processing parameters. A simple, analytical, model was set up and used to determine the temperature of the PMMA during the bonding process. As a proof of concept, the femtosecond-laser bonding of a simple hybrid PMMA-Si microfluidic device has been successfully demonstrated through dynamic leakage tests.
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spelling doaj.art-54eed0e0d77d47d5b33c5a78cd4158ce2023-04-03T05:26:41ZengNature PortfolioScientific Reports2045-23222023-03-0113111110.1038/s41598-023-31969-yBonding of PMMA to silicon by femtosecond laser pulsesFilippo Maria Conte Capodacqua0Annalisa Volpe1Caterina Gaudiuso2Antonio Ancona3Dipartimento Interateneo Di Fisica, Politecnico & Università Degli Studi di BariDipartimento Interateneo Di Fisica, Politecnico & Università Degli Studi di BariInstitute for Photonics and Nanotechnologies (IFN), National Research CouncilDipartimento Interateneo Di Fisica, Politecnico & Università Degli Studi di BariAbstract Many devices and objects, from microelectronics to microfluidics, consist of parts made from dissimilar materials, such as different polymers, metals or semiconductors. Techniques for joining such hybrid micro-devices, generally, are based on gluing or thermal processes, which all present some drawbacks. For example, these methods are unable to control the size and shape of the bonded area, and present risks of deterioration and contamination of the substrates. Ultrashort laser bonding is a non-contact and flexible technique to precisely join similar and dissimilar materials, used both for joining polymers, and polymers to metallic substrates, but not yet for joining polymers to silicon. We report on direct transmission femtosecond laser bonding of poly(methyl methacrylate) (PMMA) and silicon. The laser process was performed by focusing ultrashort laser pulses at high repetition rate at the interface between the two materials through the PMMA upper layer. The PMMA-Si bond strength was evaluated as a function of different laser processing parameters. A simple, analytical, model was set up and used to determine the temperature of the PMMA during the bonding process. As a proof of concept, the femtosecond-laser bonding of a simple hybrid PMMA-Si microfluidic device has been successfully demonstrated through dynamic leakage tests.https://doi.org/10.1038/s41598-023-31969-y
spellingShingle Filippo Maria Conte Capodacqua
Annalisa Volpe
Caterina Gaudiuso
Antonio Ancona
Bonding of PMMA to silicon by femtosecond laser pulses
Scientific Reports
title Bonding of PMMA to silicon by femtosecond laser pulses
title_full Bonding of PMMA to silicon by femtosecond laser pulses
title_fullStr Bonding of PMMA to silicon by femtosecond laser pulses
title_full_unstemmed Bonding of PMMA to silicon by femtosecond laser pulses
title_short Bonding of PMMA to silicon by femtosecond laser pulses
title_sort bonding of pmma to silicon by femtosecond laser pulses
url https://doi.org/10.1038/s41598-023-31969-y
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AT annalisavolpe bondingofpmmatosiliconbyfemtosecondlaserpulses
AT caterinagaudiuso bondingofpmmatosiliconbyfemtosecondlaserpulses
AT antonioancona bondingofpmmatosiliconbyfemtosecondlaserpulses