Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds
A visible light-mediated heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile has been established using K-modified carbon nitride (CN-K) as a recyclable semiconductor photocatalyst. This protocol, employing readily accessible alkyl <i>N</i>-hydroxyphthalimide (...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2021-05-01
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| Series: | Beilstein Journal of Organic Chemistry |
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| Online Access: | https://doi.org/10.3762/bjoc.17.89 |
| _version_ | 1818437931374739456 |
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| author | Guanglong Pan Qian Yang Wentao Wang Yurong Tang Yunfei Cai |
| author_facet | Guanglong Pan Qian Yang Wentao Wang Yurong Tang Yunfei Cai |
| author_sort | Guanglong Pan |
| collection | DOAJ |
| description | A visible light-mediated heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile has been established using K-modified carbon nitride (CN-K) as a recyclable semiconductor photocatalyst. This protocol, employing readily accessible alkyl <i>N</i>-hydroxyphthalimide (NHPI) ester as a radical initiator, allows the efficient construction of a broad array of structural diverse nitrogenous heterocyclic compounds including indolines, oxindoles, isoquinolinones, and isoquinolinediones. |
| first_indexed | 2024-12-14T17:32:31Z |
| format | Article |
| id | doaj.art-55004ffeb7024d2287c46b2c8ce3229c |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-14T17:32:31Z |
| publishDate | 2021-05-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-55004ffeb7024d2287c46b2c8ce3229c2022-12-21T22:53:04ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972021-05-011711171118010.3762/bjoc.17.891860-5397-17-89Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compoundsGuanglong Pan0Qian Yang1Wentao Wang2Yurong Tang3Yunfei Cai4School of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Chongqing 400044, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Chongqing 400044, ChinaDalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Chongqing 400044, ChinaSchool of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Chongqing 400044, ChinaA visible light-mediated heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile has been established using K-modified carbon nitride (CN-K) as a recyclable semiconductor photocatalyst. This protocol, employing readily accessible alkyl <i>N</i>-hydroxyphthalimide (NHPI) ester as a radical initiator, allows the efficient construction of a broad array of structural diverse nitrogenous heterocyclic compounds including indolines, oxindoles, isoquinolinones, and isoquinolinediones.https://doi.org/10.3762/bjoc.17.89carbon nitridecyanoalkylarylationheterocyclic compoundheterogeneous photocatalysisrecyclable |
| spellingShingle | Guanglong Pan Qian Yang Wentao Wang Yurong Tang Yunfei Cai Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds Beilstein Journal of Organic Chemistry carbon nitride cyanoalkylarylation heterocyclic compound heterogeneous photocatalysis recyclable |
| title | Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds |
| title_full | Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds |
| title_fullStr | Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds |
| title_full_unstemmed | Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds |
| title_short | Heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile: synthesis of diverse nitrogenous heterocyclic compounds |
| title_sort | heterogeneous photocatalytic cyanomethylarylation of alkenes with acetonitrile synthesis of diverse nitrogenous heterocyclic compounds |
| topic | carbon nitride cyanoalkylarylation heterocyclic compound heterogeneous photocatalysis recyclable |
| url | https://doi.org/10.3762/bjoc.17.89 |
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