Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ2N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate

In the title compound, [Cd(C10H9N4O2S)2(C3H7NO)2(H2O)]·H2O, the CdII ion displays a grossly distorted octahedral (or irregular) mer-CdN3O3 coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion,...

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Bibliographic Details
Main Author: G. M. Golzar Hossain
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811019635
Description
Summary:In the title compound, [Cd(C10H9N4O2S)2(C3H7NO)2(H2O)]·H2O, the CdII ion displays a grossly distorted octahedral (or irregular) mer-CdN3O3 coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethylformamide molecules and one water molecule. A short Cd...N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features intermolecular N—H...O, O—H...O and O—H...N hydrogen bonds.
ISSN:1600-5368