Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)
The molecular and crystal structure of a newly synthesized Co(II) complex with 2,6-diacetylpyridine bis(phenylhydrazone) (L), of the formula [CoL2]I2 are described. The reaction of warm EtOH solutions of the ligand, 2,6-diacetylpyridine bis(phenylhydrazone) and CoI2 in molar ratio 1:1 resulted in fo...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
University of Priština - Faculty of Natural Science and Mathematics, Kosovska Mitrovica
2018-01-01
|
| Series: | The University Thought: Publication in Natural Sciences |
| Subjects: | |
| Online Access: | https://scindeks-clanci.ceon.rs/data/pdf/1450-7226/2018/1450-72261802033B.pdf |
| _version_ | 1819097669303271424 |
|---|---|
| author | Belošević Svetlana Rodić Marko Radanović Mirjana Leovac Vukadin |
| author_facet | Belošević Svetlana Rodić Marko Radanović Mirjana Leovac Vukadin |
| author_sort | Belošević Svetlana |
| collection | DOAJ |
| description | The molecular and crystal structure of a newly synthesized Co(II) complex with 2,6-diacetylpyridine bis(phenylhydrazone) (L), of the formula [CoL2]I2 are described. The reaction of warm EtOH solutions of the ligand, 2,6-diacetylpyridine bis(phenylhydrazone) and CoI2 in molar ratio 1:1 resulted in formation of black single crystals of the title complex. This is the first and so far, the only metal complex with this ligand that is characterized by single crystal X-ray crystallography. Co(II) is situated in a distorted mer-octahedral surrounding of two tridentate N3 coordinated ligand molecules. Complex crystallizes in monoclinic crystal system in C2/c space group. Besides X-ray analysis, conductometric, spectroscopic and magnetic properties of the complex are investigated. |
| first_indexed | 2024-12-22T00:18:46Z |
| format | Article |
| id | doaj.art-55355661d9c24779af9f930149e7eb3c |
| institution | Directory Open Access Journal |
| issn | 1450-7226 2560-3094 |
| language | English |
| last_indexed | 2024-12-22T00:18:46Z |
| publishDate | 2018-01-01 |
| publisher | University of Priština - Faculty of Natural Science and Mathematics, Kosovska Mitrovica |
| record_format | Article |
| series | The University Thought: Publication in Natural Sciences |
| spelling | doaj.art-55355661d9c24779af9f930149e7eb3c2022-12-21T18:45:14ZengUniversity of Priština - Faculty of Natural Science and Mathematics, Kosovska MitrovicaThe University Thought: Publication in Natural Sciences1450-72262560-30942018-01-018233381450-72261802033BSynthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)Belošević Svetlana0Rodić Marko1Radanović Mirjana2Leovac Vukadin3University of Priština, Faculty of Technical Sciences, Kosovska MitrovicaUniversity of Novi Sad, Faculty of SciencesUniversity of Novi Sad, Faculty of SciencesUniversity of Novi Sad, Faculty of SciencesThe molecular and crystal structure of a newly synthesized Co(II) complex with 2,6-diacetylpyridine bis(phenylhydrazone) (L), of the formula [CoL2]I2 are described. The reaction of warm EtOH solutions of the ligand, 2,6-diacetylpyridine bis(phenylhydrazone) and CoI2 in molar ratio 1:1 resulted in formation of black single crystals of the title complex. This is the first and so far, the only metal complex with this ligand that is characterized by single crystal X-ray crystallography. Co(II) is situated in a distorted mer-octahedral surrounding of two tridentate N3 coordinated ligand molecules. Complex crystallizes in monoclinic crystal system in C2/c space group. Besides X-ray analysis, conductometric, spectroscopic and magnetic properties of the complex are investigated.https://scindeks-clanci.ceon.rs/data/pdf/1450-7226/2018/1450-72261802033B.pdfmetal complexhydrazone26-diacetylpyridine derivativestructure determination |
| spellingShingle | Belošević Svetlana Rodić Marko Radanović Mirjana Leovac Vukadin Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) The University Thought: Publication in Natural Sciences metal complex hydrazone 2 6-diacetylpyridine derivative structure determination |
| title | Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) |
| title_full | Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) |
| title_fullStr | Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) |
| title_full_unstemmed | Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) |
| title_short | Synthesis and structure of cobalt(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone) |
| title_sort | synthesis and structure of cobalt ii complex with 2 6 diacetylpyridine bis phenylhydrazone |
| topic | metal complex hydrazone 2 6-diacetylpyridine derivative structure determination |
| url | https://scindeks-clanci.ceon.rs/data/pdf/1450-7226/2018/1450-72261802033B.pdf |
| work_keys_str_mv | AT belosevicsvetlana synthesisandstructureofcobaltiicomplexwith26diacetylpyridinebisphenylhydrazone AT rodicmarko synthesisandstructureofcobaltiicomplexwith26diacetylpyridinebisphenylhydrazone AT radanovicmirjana synthesisandstructureofcobaltiicomplexwith26diacetylpyridinebisphenylhydrazone AT leovacvukadin synthesisandstructureofcobaltiicomplexwith26diacetylpyridinebisphenylhydrazone |