Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most...
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MDPI AG
2018-10-01
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Series: | Molecules |
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Online Access: | http://www.mdpi.com/1420-3049/23/10/2532 |
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author | Mahmoud Nasrollahzadeh |
author_facet | Mahmoud Nasrollahzadeh |
author_sort | Mahmoud Nasrollahzadeh |
collection | DOAJ |
description | Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed. |
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id | doaj.art-554a7f98d0e34114b52fe1d0d7d39b5f |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-13T03:42:56Z |
publishDate | 2018-10-01 |
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series | Molecules |
spelling | doaj.art-554a7f98d0e34114b52fe1d0d7d39b5f2022-12-22T00:00:53ZengMDPI AGMolecules1420-30492018-10-012310253210.3390/molecules23102532molecules23102532Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling ReactionsMahmoud Nasrollahzadeh0Department of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, IranCarbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.http://www.mdpi.com/1420-3049/23/10/2532magnetic nanoparticlespalladium complexescoupling reactions |
spellingShingle | Mahmoud Nasrollahzadeh Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions Molecules magnetic nanoparticles palladium complexes coupling reactions |
title | Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions |
title_full | Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions |
title_fullStr | Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions |
title_full_unstemmed | Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions |
title_short | Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions |
title_sort | advances in magnetic nanoparticles supported palladium complexes for coupling reactions |
topic | magnetic nanoparticles palladium complexes coupling reactions |
url | http://www.mdpi.com/1420-3049/23/10/2532 |
work_keys_str_mv | AT mahmoudnasrollahzadeh advancesinmagneticnanoparticlessupportedpalladiumcomplexesforcouplingreactions |