Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions

Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most...

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Main Author: Mahmoud Nasrollahzadeh
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/23/10/2532
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author Mahmoud Nasrollahzadeh
author_facet Mahmoud Nasrollahzadeh
author_sort Mahmoud Nasrollahzadeh
collection DOAJ
description Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.
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spelling doaj.art-554a7f98d0e34114b52fe1d0d7d39b5f2022-12-22T00:00:53ZengMDPI AGMolecules1420-30492018-10-012310253210.3390/molecules23102532molecules23102532Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling ReactionsMahmoud Nasrollahzadeh0Department of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, IranCarbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.http://www.mdpi.com/1420-3049/23/10/2532magnetic nanoparticlespalladium complexescoupling reactions
spellingShingle Mahmoud Nasrollahzadeh
Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
Molecules
magnetic nanoparticles
palladium complexes
coupling reactions
title Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
title_full Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
title_fullStr Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
title_full_unstemmed Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
title_short Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions
title_sort advances in magnetic nanoparticles supported palladium complexes for coupling reactions
topic magnetic nanoparticles
palladium complexes
coupling reactions
url http://www.mdpi.com/1420-3049/23/10/2532
work_keys_str_mv AT mahmoudnasrollahzadeh advancesinmagneticnanoparticlessupportedpalladiumcomplexesforcouplingreactions