A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) dimethylformamide monosolvate

A new example of intramolecular C—H...Ni anagostic interactions: synthesis, crystal structure and Hirshfeld analysis of cis-bis[4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) dimethylformamide monosolvate

The reaction of NiII acetate tetrahydrate with 4-methyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide in a 2:1 molar ratio and recrystallization from dimethylformamide yielded the title compound, [Ni(C12H14N3S)2]·C3H7NO. The ligands act as monoanionic κ2N1,S-donors, forming five-...

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Bibliographic Details
Main Authors: Adriano Bof de Oliveira, Johannes Beck, Sônia Elizabeth Brown S. Mellone, Jörg Daniels
Format: Article
Language:English
Published: International Union of Crystallography 2017-06-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
Ni—H anagostic interaction
nickel-thiosemicarbazone cis complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017007198

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http://scripts.iucr.org/cgi-bin/paper?S2056989017007198

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