Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation
In this work, we have developed a simple and very effective experimental strategy for the reaction of Knoevenagel via the condensation of aromatic aldehydes substituted with active methylene compounds in the presence of hybrid nanocomposites xMCl2-yNaPO3 (MCl2 = 2,2′-dibenzimidazolyl butane dichlorh...
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| Format: | Article |
| Language: | English |
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Elsevier
2020-11-01
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| Series: | Heliyon |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844020321368 |
| _version_ | 1818565918670716928 |
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| author | Zakaria Benzekri Halima El Aadad Sarra Sibous Houda Serrar Said Boukhris Abdelkrim Chahine Abdelaziz Souizi |
| author_facet | Zakaria Benzekri Halima El Aadad Sarra Sibous Houda Serrar Said Boukhris Abdelkrim Chahine Abdelaziz Souizi |
| author_sort | Zakaria Benzekri |
| collection | DOAJ |
| description | In this work, we have developed a simple and very effective experimental strategy for the reaction of Knoevenagel via the condensation of aromatic aldehydes substituted with active methylene compounds in the presence of hybrid nanocomposites xMCl2-yNaPO3 (MCl2 = 2,2′-dibenzimidazolyl butane dichlorhydrates), under ecological conditions. The Phosphate-Benzimidazole hybrid nanocomposite as heterogeneous catalysts has demonstrated a high catalytic activity for the Knoevenagel condensation in ethanol as an ecological solvent. It has several advantages such as light reaction conditions, a simple and ecological working procedure. Meanwhile, xMCl2-yNaPO3 can be recovered by simple filtration and this catalytic system having an interesting lifetime (five cycles) with no decrease in activity. |
| first_indexed | 2024-12-14T01:47:01Z |
| format | Article |
| id | doaj.art-557b505bede9482e998488688d65798c |
| institution | Directory Open Access Journal |
| issn | 2405-8440 |
| language | English |
| last_indexed | 2024-12-14T01:47:01Z |
| publishDate | 2020-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Heliyon |
| spelling | doaj.art-557b505bede9482e998488688d65798c2022-12-21T23:21:31ZengElsevierHeliyon2405-84402020-11-01611e05293Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensationZakaria Benzekri0Halima El Aadad1Sarra Sibous2Houda Serrar3Said Boukhris4Abdelkrim Chahine5Abdelaziz Souizi6Laboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, BO 133, 14000, Kenitra, Morocco; Corresponding author.Laboratory of Physico-Chemistry of Vitreous and Crystallized Materials (LPCVCM), Faculty of Science, Ibn Tofail University, BP 133, 14000 Kenitra, MoroccoLaboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, BO 133, 14000, Kenitra, MoroccoLaboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, BO 133, 14000, Kenitra, MoroccoLaboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, BO 133, 14000, Kenitra, MoroccoLaboratory of Physico-Chemistry of Vitreous and Crystallized Materials (LPCVCM), Faculty of Science, Ibn Tofail University, BP 133, 14000 Kenitra, MoroccoLaboratory of Organic Chemistry, Organometallic and Theoretical, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, BO 133, 14000, Kenitra, MoroccoIn this work, we have developed a simple and very effective experimental strategy for the reaction of Knoevenagel via the condensation of aromatic aldehydes substituted with active methylene compounds in the presence of hybrid nanocomposites xMCl2-yNaPO3 (MCl2 = 2,2′-dibenzimidazolyl butane dichlorhydrates), under ecological conditions. The Phosphate-Benzimidazole hybrid nanocomposite as heterogeneous catalysts has demonstrated a high catalytic activity for the Knoevenagel condensation in ethanol as an ecological solvent. It has several advantages such as light reaction conditions, a simple and ecological working procedure. Meanwhile, xMCl2-yNaPO3 can be recovered by simple filtration and this catalytic system having an interesting lifetime (five cycles) with no decrease in activity.http://www.sciencedirect.com/science/article/pii/S2405844020321368Organic chemistryEcological conditionsMCl2-NaPO3Hybrid nanocompositesPhosphateHeterogeneous catalytic |
| spellingShingle | Zakaria Benzekri Halima El Aadad Sarra Sibous Houda Serrar Said Boukhris Abdelkrim Chahine Abdelaziz Souizi Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation Heliyon Organic chemistry Ecological conditions MCl2-NaPO3 Hybrid nanocomposites Phosphate Heterogeneous catalytic |
| title | Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation |
| title_full | Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation |
| title_fullStr | Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation |
| title_full_unstemmed | Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation |
| title_short | Improvement of the catalytic performance of hybrid nanocomposite based on phosphate-benzimidazole in Knoevenagel condensation |
| title_sort | improvement of the catalytic performance of hybrid nanocomposite based on phosphate benzimidazole in knoevenagel condensation |
| topic | Organic chemistry Ecological conditions MCl2-NaPO3 Hybrid nanocomposites Phosphate Heterogeneous catalytic |
| url | http://www.sciencedirect.com/science/article/pii/S2405844020321368 |
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