Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes
In this work, a high solids acrylic copolymer polyol (poly(MMA/BA/HEMA/AA)) was synthesized from the polymerization of methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA) and acrylic acid (AA) and was added to the polyaspartic resin. The polyaspartic-polyol mixtures reac...
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| Format: | Article |
| Language: | English |
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Turkish Chemical Society
2023-08-01
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| Series: | Journal of the Turkish Chemical Society, Section A: Chemistry |
| Subjects: | |
| Online Access: | https://dergipark.org.tr/tr/pub/jotcsa/issue/78393/1216320 |
| _version_ | 1797689188495130624 |
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| author | Cemil DIZMAN Elif CERRAHOĞLU KAÇAKGİL Levent BABAYİĞİT Caner ARAR |
| author_facet | Cemil DIZMAN Elif CERRAHOĞLU KAÇAKGİL Levent BABAYİĞİT Caner ARAR |
| author_sort | Cemil DIZMAN |
| collection | DOAJ |
| description | In this work, a high solids acrylic copolymer polyol (poly(MMA/BA/HEMA/AA)) was synthesized from the polymerization of methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA) and acrylic acid (AA) and was added to the polyaspartic resin. The polyaspartic-polyol mixtures reacted with polyisocyanates to create hybrid polyurethane-polyaspartic hybrid coatings. Different amounts of synthesized acrylic copolymer (5, 10, and 20% of total resin mixture) were mixed into polyaspartic resin and subsequently reacted with polyisocyanates in a 1:1 molar ratio. The characterization of the polymer was performed with Gel Permeation Chromatography (GPC), Fourier-Transform Infrared-Attenuated Total Reflection (FTIR-ATR) and Differential Scanning Calorimetry (DSC). The determination of physical and mechanical properties of the hybrid coatings was accomplished by hardness, glossiness, abrasion, stress-strain, corrosion, and impact tests. The results indicated that by adding high solids acrylic copolymer (HSAC), the drawbacks of polyaspartic resin (short pot life, hardness and brittleness, and poor adhesiveness) have been largely eliminated without reducing its intrinsic properties. The pot life increased from 16 minutes to 27 minutes and shore D hardness decreased from 60-65 to 52-55 as the polyol content increased in the mixtures. The acrylic polyols and aspartic mixtures may be used in the preparation of paints and varnishes applied on concrete, metal, and wood surfaces. |
| first_indexed | 2024-03-12T01:42:18Z |
| format | Article |
| id | doaj.art-5593fcd3f31941648f2e088110b6bc7a |
| institution | Directory Open Access Journal |
| issn | 2149-0120 |
| language | English |
| last_indexed | 2024-03-12T01:42:18Z |
| publishDate | 2023-08-01 |
| publisher | Turkish Chemical Society |
| record_format | Article |
| series | Journal of the Turkish Chemical Society, Section A: Chemistry |
| spelling | doaj.art-5593fcd3f31941648f2e088110b6bc7a2023-09-10T07:00:34ZengTurkish Chemical SocietyJournal of the Turkish Chemical Society, Section A: Chemistry2149-01202023-08-01103605620https://doi.org/10.18596/jotcsa.1216320 Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes Cemil DIZMAN0https://orcid.org/0000-0002-1780-3008Elif CERRAHOĞLU KAÇAKGİL 1https://orcid.org/0000-0002-6548-0944Levent BABAYİĞİT 2https://orcid.org/0000-0001-6286-5083Caner ARAR3https://orcid.org/0000-0001-7914-272X İZEL KİMYA ARGE MERKEZİ İZEL KİMYA ARGE MERKEZİ İZEL KİMYA ARGE MERKEZİ İZEL KİMYA ARGE MERKEZİ In this work, a high solids acrylic copolymer polyol (poly(MMA/BA/HEMA/AA)) was synthesized from the polymerization of methyl methacrylate (MMA), butyl acrylate (BA), hydroxyethyl methacrylate (HEMA) and acrylic acid (AA) and was added to the polyaspartic resin. The polyaspartic-polyol mixtures reacted with polyisocyanates to create hybrid polyurethane-polyaspartic hybrid coatings. Different amounts of synthesized acrylic copolymer (5, 10, and 20% of total resin mixture) were mixed into polyaspartic resin and subsequently reacted with polyisocyanates in a 1:1 molar ratio. The characterization of the polymer was performed with Gel Permeation Chromatography (GPC), Fourier-Transform Infrared-Attenuated Total Reflection (FTIR-ATR) and Differential Scanning Calorimetry (DSC). The determination of physical and mechanical properties of the hybrid coatings was accomplished by hardness, glossiness, abrasion, stress-strain, corrosion, and impact tests. The results indicated that by adding high solids acrylic copolymer (HSAC), the drawbacks of polyaspartic resin (short pot life, hardness and brittleness, and poor adhesiveness) have been largely eliminated without reducing its intrinsic properties. The pot life increased from 16 minutes to 27 minutes and shore D hardness decreased from 60-65 to 52-55 as the polyol content increased in the mixtures. The acrylic polyols and aspartic mixtures may be used in the preparation of paints and varnishes applied on concrete, metal, and wood surfaces.https://dergipark.org.tr/tr/pub/jotcsa/issue/78393/1216320acrylic copolymercoatinghigh solids acrylic polyolspaintpolyaspartic |
| spellingShingle | Cemil DIZMAN Elif CERRAHOĞLU KAÇAKGİL Levent BABAYİĞİT Caner ARAR Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes Journal of the Turkish Chemical Society, Section A: Chemistry acrylic copolymer coating high solids acrylic polyols paint polyaspartic |
| title | Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes |
| title_full | Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes |
| title_fullStr | Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes |
| title_full_unstemmed | Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes |
| title_short | Preparation and Characterization of Polyaspartic and a High Solids Acrylic Copolymer Polyol Based Polyurethanes |
| title_sort | preparation and characterization of polyaspartic and a high solids acrylic copolymer polyol based polyurethanes |
| topic | acrylic copolymer coating high solids acrylic polyols paint polyaspartic |
| url | https://dergipark.org.tr/tr/pub/jotcsa/issue/78393/1216320 |
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