Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
The asymmetric unit of the title compound, C6H16N+·C3H2N3S3−, contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811034271 |
| _version_ | 1798017852691709952 |
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| author | He-Ping Li Seik Weng Ng |
| author_facet | He-Ping Li Seik Weng Ng |
| author_sort | He-Ping Li |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C6H16N+·C3H2N3S3−, contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic double-bond S atoms. The anions interact by N—H...S hydrogen bonds to generate a chain running along [110]. The triethylammonium cations are hydrogen bonded to the anions with the ammonium H atom forming a hydrogen bond to the negatively-charged N atom of the anion. In the crystal structure, both triethylammonium cations are disordered over two orientations with equal occupancies. |
| first_indexed | 2024-04-11T16:14:11Z |
| format | Article |
| id | doaj.art-559f602a1d4a4468a72c42ac957b1356 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:14:11Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-559f602a1d4a4468a72c42ac957b13562022-12-22T04:14:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2473o247310.1107/S1600536811034271Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ideHe-Ping LiSeik Weng NgThe asymmetric unit of the title compound, C6H16N+·C3H2N3S3−, contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic double-bond S atoms. The anions interact by N—H...S hydrogen bonds to generate a chain running along [110]. The triethylammonium cations are hydrogen bonded to the anions with the ammonium H atom forming a hydrogen bond to the negatively-charged N atom of the anion. In the crystal structure, both triethylammonium cations are disordered over two orientations with equal occupancies.http://scripts.iucr.org/cgi-bin/paper?S1600536811034271 |
| spellingShingle | He-Ping Li Seik Weng Ng Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide Acta Crystallographica Section E |
| title | Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
| title_full | Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
| title_fullStr | Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
| title_full_unstemmed | Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
| title_short | Triethylammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide |
| title_sort | triethylammonium 2 4 6 trisulfanylidene 1 3 5 triazinan 1 ide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811034271 |
| work_keys_str_mv | AT hepingli triethylammonium246trisulfanylidene135triazinan1ide AT seikwengng triethylammonium246trisulfanylidene135triazinan1ide |