Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures

In the current experimental work, pure ZnO and Ba-doped ZnO nanorods have been prepared by implementing a facile wet chemical technique. XRD study reveals the formation of the hexagonal wurtzite phase of pure ZnO and Ba-doped ZnO nanorods. Interestingly, Ba-doped ZnO nanorods show very good absorpti...

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Main Authors: J. Samuel, T.S. Franklin Rajesh, C.S. Biju, S. Sahaya Jude Dhas, S. Usharani
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Results in Optics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666950123001347
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author J. Samuel
T.S. Franklin Rajesh
C.S. Biju
S. Sahaya Jude Dhas
S. Usharani
author_facet J. Samuel
T.S. Franklin Rajesh
C.S. Biju
S. Sahaya Jude Dhas
S. Usharani
author_sort J. Samuel
collection DOAJ
description In the current experimental work, pure ZnO and Ba-doped ZnO nanorods have been prepared by implementing a facile wet chemical technique. XRD study reveals the formation of the hexagonal wurtzite phase of pure ZnO and Ba-doped ZnO nanorods. Interestingly, Ba-doped ZnO nanorods show very good absorption in the UVA (93% at 351 nm), UVB (90% at 300 nm) and UVC (61% at 220 nm) regions. The obtained results of the UV–visible absorbance study validate in such a way that the Ba-doped ZnO nanorods could be a better bet to be utilized as a UV blocker for the next generation of UV shielding materials. The Photoluminescence spectrum of Ba-doped ZnO nanoparticles reveals widespread UV–Visible bands between 350 and 600 nm. Also, the zone of inhibition is found to be 15 nm for both bacterial strains S.aures and E.coli and implies excellent antibacterial activity. Interestingly, the outcome as observed in the zone of inhibition towards S. aureus and E. coli in the present study is found to be higher than many doped ZnO and Ba-doped metal oxide nanostructures. The observed experimental results via the aforementioned characterizations imply that the synthesized samples possess the potential ingredients required for the applications related to the field of health care.
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spelling doaj.art-55a9eebf471d426380f7eaa27506ea712023-08-29T04:18:15ZengElsevierResults in Optics2666-95012023-07-0112100482Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructuresJ. Samuel0T.S. Franklin Rajesh1C.S. Biju2S. Sahaya Jude Dhas3S. Usharani4Reg.No: 20123082131014, Research scholar, Department of Physics and Research Centre, Malankara Catholic College, Mariagiri-629153, Tamilnadu, India; Affiliated to Manonmaniam Sundaranar University, Abishekapatti-627012, Tirunelveli, Tamilnadu, IndiaDepartment of Chemistry, Velammal Vidhyashram, Surapet, Chennai-600066, Tamilnadu, IndiaFormerly Assistant Professor, Department of Physics, Malankara Catholic College, Mariagiri, Kaliakkavilai-629153, Tamil Nadu, India; Assistant Professor, Department of Physics, St. Alphonsa College of Arts and Science, Soosaipuram, Karinkal-629159, Tamil Nadu, India; Corresponding authors at: Department of Physics, St. Alphonsa College of Arts and Science, Soosaipuram, Karinkal-629159, Tamil Nadu, India (C.S. Biju).Department of Physics, Kings Engineering College, Sriperumbudur-602117, Chennai, Tamilnadu, India; Corresponding authors at: Department of Physics, St. Alphonsa College of Arts and Science, Soosaipuram, Karinkal-629159, Tamil Nadu, India (C.S. Biju).Department of Chemistry, S.I.V.E.T College, Gowrivakkam, Chennai-600073, Tamilnadu, IndiaIn the current experimental work, pure ZnO and Ba-doped ZnO nanorods have been prepared by implementing a facile wet chemical technique. XRD study reveals the formation of the hexagonal wurtzite phase of pure ZnO and Ba-doped ZnO nanorods. Interestingly, Ba-doped ZnO nanorods show very good absorption in the UVA (93% at 351 nm), UVB (90% at 300 nm) and UVC (61% at 220 nm) regions. The obtained results of the UV–visible absorbance study validate in such a way that the Ba-doped ZnO nanorods could be a better bet to be utilized as a UV blocker for the next generation of UV shielding materials. The Photoluminescence spectrum of Ba-doped ZnO nanoparticles reveals widespread UV–Visible bands between 350 and 600 nm. Also, the zone of inhibition is found to be 15 nm for both bacterial strains S.aures and E.coli and implies excellent antibacterial activity. Interestingly, the outcome as observed in the zone of inhibition towards S. aureus and E. coli in the present study is found to be higher than many doped ZnO and Ba-doped metal oxide nanostructures. The observed experimental results via the aforementioned characterizations imply that the synthesized samples possess the potential ingredients required for the applications related to the field of health care.http://www.sciencedirect.com/science/article/pii/S2666950123001347Wet chemical synthesisDopingRaman spectrumPhotoluminescenceUV blockerBand gap
spellingShingle J. Samuel
T.S. Franklin Rajesh
C.S. Biju
S. Sahaya Jude Dhas
S. Usharani
Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
Results in Optics
Wet chemical synthesis
Doping
Raman spectrum
Photoluminescence
UV blocker
Band gap
title Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
title_full Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
title_fullStr Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
title_full_unstemmed Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
title_short Synthesis, structural, photoluminescence, ultraviolet blocking and antibacterial performances of Ba-doped ZnO nanostructures
title_sort synthesis structural photoluminescence ultraviolet blocking and antibacterial performances of ba doped zno nanostructures
topic Wet chemical synthesis
Doping
Raman spectrum
Photoluminescence
UV blocker
Band gap
url http://www.sciencedirect.com/science/article/pii/S2666950123001347
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