Valence bond phases of herbertsmithite and related copper kagome materials

Recent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this miner...

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Main Authors: M. R. Norman, N. J. Laurita, D. Hsieh
Format: Article
Language:English
Published: American Physical Society 2020-01-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.2.013055
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author M. R. Norman
N. J. Laurita
D. Hsieh
author_facet M. R. Norman
N. J. Laurita
D. Hsieh
author_sort M. R. Norman
collection DOAJ
description Recent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this mineral class, along with related copper kagome oxides and fluorides, relate these to possible valence bond patterns, and comment on their relevance to the physics of these interesting materials.
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spelling doaj.art-55ac93e74d4b4b56ad022afb25a2949a2024-04-12T16:48:50ZengAmerican Physical SocietyPhysical Review Research2643-15642020-01-012101305510.1103/PhysRevResearch.2.013055Valence bond phases of herbertsmithite and related copper kagome materialsM. R. NormanN. J. LauritaD. HsiehRecent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this mineral class, along with related copper kagome oxides and fluorides, relate these to possible valence bond patterns, and comment on their relevance to the physics of these interesting materials.http://doi.org/10.1103/PhysRevResearch.2.013055
spellingShingle M. R. Norman
N. J. Laurita
D. Hsieh
Valence bond phases of herbertsmithite and related copper kagome materials
Physical Review Research
title Valence bond phases of herbertsmithite and related copper kagome materials
title_full Valence bond phases of herbertsmithite and related copper kagome materials
title_fullStr Valence bond phases of herbertsmithite and related copper kagome materials
title_full_unstemmed Valence bond phases of herbertsmithite and related copper kagome materials
title_short Valence bond phases of herbertsmithite and related copper kagome materials
title_sort valence bond phases of herbertsmithite and related copper kagome materials
url http://doi.org/10.1103/PhysRevResearch.2.013055
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