Valence bond phases of herbertsmithite and related copper kagome materials
Recent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this miner...
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Format: | Article |
Language: | English |
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American Physical Society
2020-01-01
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Series: | Physical Review Research |
Online Access: | http://doi.org/10.1103/PhysRevResearch.2.013055 |
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author | M. R. Norman N. J. Laurita D. Hsieh |
author_facet | M. R. Norman N. J. Laurita D. Hsieh |
author_sort | M. R. Norman |
collection | DOAJ |
description | Recent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this mineral class, along with related copper kagome oxides and fluorides, relate these to possible valence bond patterns, and comment on their relevance to the physics of these interesting materials. |
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id | doaj.art-55ac93e74d4b4b56ad022afb25a2949a |
institution | Directory Open Access Journal |
issn | 2643-1564 |
language | English |
last_indexed | 2024-04-24T10:29:05Z |
publishDate | 2020-01-01 |
publisher | American Physical Society |
record_format | Article |
series | Physical Review Research |
spelling | doaj.art-55ac93e74d4b4b56ad022afb25a2949a2024-04-12T16:48:50ZengAmerican Physical SocietyPhysical Review Research2643-15642020-01-012101305510.1103/PhysRevResearch.2.013055Valence bond phases of herbertsmithite and related copper kagome materialsM. R. NormanN. J. LauritaD. HsiehRecent evidence from magnetic torque, electron spin resonance, and second harmonic generation indicate that the prototypical quantum spin liquid candidate, herbertsmithite, has a symmetry lower than its x-ray refined trigonal space group. Here we consider known and possible distortions of this mineral class, along with related copper kagome oxides and fluorides, relate these to possible valence bond patterns, and comment on their relevance to the physics of these interesting materials.http://doi.org/10.1103/PhysRevResearch.2.013055 |
spellingShingle | M. R. Norman N. J. Laurita D. Hsieh Valence bond phases of herbertsmithite and related copper kagome materials Physical Review Research |
title | Valence bond phases of herbertsmithite and related copper kagome materials |
title_full | Valence bond phases of herbertsmithite and related copper kagome materials |
title_fullStr | Valence bond phases of herbertsmithite and related copper kagome materials |
title_full_unstemmed | Valence bond phases of herbertsmithite and related copper kagome materials |
title_short | Valence bond phases of herbertsmithite and related copper kagome materials |
title_sort | valence bond phases of herbertsmithite and related copper kagome materials |
url | http://doi.org/10.1103/PhysRevResearch.2.013055 |
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