A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II)
The title compound, [Fe(C9H10BN6)2], is a polymorph of a compound reported previously [Oliver et al. (1980). Inorg. Chem. 19, 165–168]. In the previous report, the compound crystallized in the monoclinic space group P21/c (Z = 4), whereas the crystal symmetry of the compound reported h...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811025839 |
| _version_ | 1828137710235156480 |
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| author | Zhong-Hai Ni Guo-Ling Li Rui Ma Jing Nie |
| author_facet | Zhong-Hai Ni Guo-Ling Li Rui Ma Jing Nie |
| author_sort | Zhong-Hai Ni |
| collection | DOAJ |
| description | The title compound, [Fe(C9H10BN6)2], is a polymorph of a compound reported previously [Oliver et al. (1980). Inorg. Chem. 19, 165–168]. In the previous report, the compound crystallized in the monoclinic space group P21/c (Z = 4), whereas the crystal symmetry of the compound reported here is tetragonal (P42/ncm, Z = 4). The molecular structure is comprised of two hydrotris(1-pyrazolyl)borate ligands (Tp−) and a central FeII ion, which is coordinated by six pyrazole N atoms from two two Tp− ligands, yielding a distorted bipyramidal FeN6 geometry. The complete molecule exhibits symmetry 2/m. |
| first_indexed | 2024-04-11T18:24:08Z |
| format | Article |
| id | doaj.art-55b5eb3fe8d0451f870b222fbdc9a4df |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:24:08Z |
| publishDate | 2011-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-55b5eb3fe8d0451f870b222fbdc9a4df2022-12-22T04:09:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1033m103310.1107/S1600536811025839A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II)Zhong-Hai NiGuo-Ling LiRui MaJing NieThe title compound, [Fe(C9H10BN6)2], is a polymorph of a compound reported previously [Oliver et al. (1980). Inorg. Chem. 19, 165–168]. In the previous report, the compound crystallized in the monoclinic space group P21/c (Z = 4), whereas the crystal symmetry of the compound reported here is tetragonal (P42/ncm, Z = 4). The molecular structure is comprised of two hydrotris(1-pyrazolyl)borate ligands (Tp−) and a central FeII ion, which is coordinated by six pyrazole N atoms from two two Tp− ligands, yielding a distorted bipyramidal FeN6 geometry. The complete molecule exhibits symmetry 2/m.http://scripts.iucr.org/cgi-bin/paper?S1600536811025839 |
| spellingShingle | Zhong-Hai Ni Guo-Ling Li Rui Ma Jing Nie A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) Acta Crystallographica Section E |
| title | A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) |
| title_full | A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) |
| title_fullStr | A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) |
| title_full_unstemmed | A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) |
| title_short | A tetragonal polymorph of bis[hydrotris(pyrazol-1-yl)borato]iron(II) |
| title_sort | tetragonal polymorph of bis hydrotris pyrazol 1 yl borato iron ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811025839 |
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