Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution

The electrocatalytic properties of a SiC particle-modified glassy carbon electrode (MGC) for adrenaline oxidation were studied by cyclic voltammetry, double-potential step chronoculometry and electrochemical impedance spectroscopy in a pH 7.4 physiological Kres–Ringer phosphate buffer (KRPB) solutio...

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Main Authors: Yu Zhang-Yu, Kong De-Sheng, Wu Shu-Xin, Wang Lei, Wang Hanf-Qing
Format: Article
Language:English
Published: Serbian Chemical Society 2005-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2005/0352-51390505745Y.pdf
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author Yu Zhang-Yu
Kong De-Sheng
Wu Shu-Xin
Wang Lei
Wang Hanf-Qing
author_facet Yu Zhang-Yu
Kong De-Sheng
Wu Shu-Xin
Wang Lei
Wang Hanf-Qing
author_sort Yu Zhang-Yu
collection DOAJ
description The electrocatalytic properties of a SiC particle-modified glassy carbon electrode (MGC) for adrenaline oxidation were studied by cyclic voltammetry, double-potential step chronoculometry and electrochemical impedance spectroscopy in a pH 7.4 physiological Kres–Ringer phosphate buffer (KRPB) solution. It was shown that modification of the electrode with SiC particles has a marked electrocatalytic effect on the electrochemical reaction of adrenaline, i.e., the activity and the reversibility of the MGC electrode were significantly improved compared to an unmodified electrode. This was attributed to the adsorption effect of the electroactive adrenaline molecules on the MGC electrode surface. .
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spelling doaj.art-55bdcd4c50f44c4889c5ad3720672f562022-12-21T20:24:51ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212005-01-0170574575210.2298/JSC0505745Y0352-51390505745YElectrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solutionYu Zhang-Yu0Kong De-Sheng1Wu Shu-Xin2Wang Lei3Wang Hanf-Qing4Department of Chemistry, Qufu Normal University, Qufu, Shandong, ChinaDepartment of Chemistry, Qufu Normal University, Qufu, Shandong, ChinaDepartment of Chemistry, Qufu Normal University, Qufu, Shandong, ChinaDepartment of Chemistry, Qufu Normal University, Qufu, Shandong, ChinaLanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, ChinaThe electrocatalytic properties of a SiC particle-modified glassy carbon electrode (MGC) for adrenaline oxidation were studied by cyclic voltammetry, double-potential step chronoculometry and electrochemical impedance spectroscopy in a pH 7.4 physiological Kres–Ringer phosphate buffer (KRPB) solution. It was shown that modification of the electrode with SiC particles has a marked electrocatalytic effect on the electrochemical reaction of adrenaline, i.e., the activity and the reversibility of the MGC electrode were significantly improved compared to an unmodified electrode. This was attributed to the adsorption effect of the electroactive adrenaline molecules on the MGC electrode surface. .http://www.doiserbia.nb.rs/img/doi/0352-5139/2005/0352-51390505745Y.pdfadrenalinesic particleglassy carbonelectrocatalysis.
spellingShingle Yu Zhang-Yu
Kong De-Sheng
Wu Shu-Xin
Wang Lei
Wang Hanf-Qing
Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
Journal of the Serbian Chemical Society
adrenaline
sic particle
glassy carbon
electrocatalysis.
title Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
title_full Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
title_fullStr Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
title_full_unstemmed Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
title_short Electrocatalysis of a SiC particle-modified glassy carbon electrode for the oxidation of adrenaline in a KRPB physiological solution
title_sort electrocatalysis of a sic particle modified glassy carbon electrode for the oxidation of adrenaline in a krpb physiological solution
topic adrenaline
sic particle
glassy carbon
electrocatalysis.
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2005/0352-51390505745Y.pdf
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AT kongdesheng electrocatalysisofasicparticlemodifiedglassycarbonelectrodefortheoxidationofadrenalineinakrpbphysiologicalsolution
AT wushuxin electrocatalysisofasicparticlemodifiedglassycarbonelectrodefortheoxidationofadrenalineinakrpbphysiologicalsolution
AT wanglei electrocatalysisofasicparticlemodifiedglassycarbonelectrodefortheoxidationofadrenalineinakrpbphysiologicalsolution
AT wanghanfqing electrocatalysisofasicparticlemodifiedglassycarbonelectrodefortheoxidationofadrenalineinakrpbphysiologicalsolution