Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates
Orange solid tetrabutylammonium fluorochromate, (C4H9)4NCrO3F, TBAFC, is easily synthesized by the reaction of tetrabutylammonium fluoride with CrO3 in a 1:1 mole ratio. Tetrabutylammonium fluorochromate(VI) is a versatile reagent for the effective and selective oxidation of organic substrates, in p...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2005-11-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.shd.org.yu/HtDocs/SHD/vol70/No11/JSCS_V70_No11-01.pdf |
| _version_ | 1819027765184167936 |
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| author | SHAHRIARE GHAMMAMI SEYED ABOLFAZL SEYED SAJADI |
| author_facet | SHAHRIARE GHAMMAMI SEYED ABOLFAZL SEYED SAJADI |
| author_sort | SHAHRIARE GHAMMAMI |
| collection | DOAJ |
| description | Orange solid tetrabutylammonium fluorochromate, (C4H9)4NCrO3F, TBAFC, is easily synthesized by the reaction of tetrabutylammonium fluoride with CrO3 in a 1:1 mole ratio. Tetrabutylammonium fluorochromate(VI) is a versatile reagent for the effective and selective oxidation of organic substrates, in particular of alcohols, under mild conditions. The facile oxidation of triphenylphosphine to triphenylphosphine oxide by TBAFC in CH3CN provides clear evidence for an oxygen-transfer reaction. |
| first_indexed | 2024-12-21T05:47:40Z |
| format | Article |
| id | doaj.art-55d6ccbbfe08465e868b8ef81c9b8c08 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-21T05:47:40Z |
| publishDate | 2005-11-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-55d6ccbbfe08465e868b8ef81c9b8c082022-12-21T19:14:05ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392005-11-01701112431248Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substratesSHAHRIARE GHAMMAMISEYED ABOLFAZL SEYED SAJADIOrange solid tetrabutylammonium fluorochromate, (C4H9)4NCrO3F, TBAFC, is easily synthesized by the reaction of tetrabutylammonium fluoride with CrO3 in a 1:1 mole ratio. Tetrabutylammonium fluorochromate(VI) is a versatile reagent for the effective and selective oxidation of organic substrates, in particular of alcohols, under mild conditions. The facile oxidation of triphenylphosphine to triphenylphosphine oxide by TBAFC in CH3CN provides clear evidence for an oxygen-transfer reaction.http://www.shd.org.yu/HtDocs/SHD/vol70/No11/JSCS_V70_No11-01.pdfoxidantchromium(VI) reagenttetrabutylammonium fluorochromateoxidationorganic substrates |
| spellingShingle | SHAHRIARE GHAMMAMI SEYED ABOLFAZL SEYED SAJADI Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates Journal of the Serbian Chemical Society oxidant chromium(VI) reagent tetrabutylammonium fluorochromate oxidation organic substrates |
| title | Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates |
| title_full | Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates |
| title_fullStr | Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates |
| title_full_unstemmed | Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates |
| title_short | Tetrabutylammonium fluorochromate(VI) (TBAFC): a mild and efficient reagent for oxidation of organic substrates |
| title_sort | tetrabutylammonium fluorochromate vi tbafc a mild and efficient reagent for oxidation of organic substrates |
| topic | oxidant chromium(VI) reagent tetrabutylammonium fluorochromate oxidation organic substrates |
| url | http://www.shd.org.yu/HtDocs/SHD/vol70/No11/JSCS_V70_No11-01.pdf |
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