Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions

Field and laboratory investigations were conducted to characterize the composition of petroleum hydrocarbons in oily sludge and the underlying contaminated soils in a decommissioned oilfield waste pit in Kuwait. The results show that the petroleum hydrocarbon composition in the oily sludge and conta...

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Main Authors: Hamad Al-Mebayedh, Anyi Niu, Chuxia Lin
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/12/3/1355
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author Hamad Al-Mebayedh
Anyi Niu
Chuxia Lin
author_facet Hamad Al-Mebayedh
Anyi Niu
Chuxia Lin
author_sort Hamad Al-Mebayedh
collection DOAJ
description Field and laboratory investigations were conducted to characterize the composition of petroleum hydrocarbons in oily sludge and the underlying contaminated soils in a decommissioned oilfield waste pit in Kuwait. The results show that the petroleum hydrocarbon composition in the oily sludge and contaminated soils was spatially variable. Highly toxic petroleum hydrocarbon species such as BTEX and PAHs were generally lacking, and both sludge- and soil-borne hydrocarbons were dominated by long-chain petroleum hydrocarbons. The soil contamination depth was generally very shallow although localized deep profiles (>0.5 m) were found. A loose relationship was established between TPH in the sludge and that in the underlying soil. On average, the soil had a greater percentage of shorter-chain hydrocarbon fractions (either aliphatics or aromatics), as compared to the sludge. The environmental risk from the oily sludge and contaminated soils is considered to be relatively low. For cost-effective management of the environmental risk of decommissioning an oilfield waste pit, containment of the sludge and contaminated soils using a soil-capping approach may be sufficient to minimize the possible adverse environmental impacts from the decommissioned waste pit, and this may represent an option that is superior to other costly remediation strategies.
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spelling doaj.art-55e687d890d64fdca2fd450a7d9c66792023-11-23T15:56:13ZengMDPI AGApplied Sciences2076-34172022-01-01123135510.3390/app12031355Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert ConditionsHamad Al-Mebayedh0Anyi Niu1Chuxia Lin2School of Science, Engineering and Environment, University of Salford, Greater Manchester, Salford M5 4WT, UKSchool of Science, Engineering and Environment, University of Salford, Greater Manchester, Salford M5 4WT, UKSchool of Science, Engineering and Environment, University of Salford, Greater Manchester, Salford M5 4WT, UKField and laboratory investigations were conducted to characterize the composition of petroleum hydrocarbons in oily sludge and the underlying contaminated soils in a decommissioned oilfield waste pit in Kuwait. The results show that the petroleum hydrocarbon composition in the oily sludge and contaminated soils was spatially variable. Highly toxic petroleum hydrocarbon species such as BTEX and PAHs were generally lacking, and both sludge- and soil-borne hydrocarbons were dominated by long-chain petroleum hydrocarbons. The soil contamination depth was generally very shallow although localized deep profiles (>0.5 m) were found. A loose relationship was established between TPH in the sludge and that in the underlying soil. On average, the soil had a greater percentage of shorter-chain hydrocarbon fractions (either aliphatics or aromatics), as compared to the sludge. The environmental risk from the oily sludge and contaminated soils is considered to be relatively low. For cost-effective management of the environmental risk of decommissioning an oilfield waste pit, containment of the sludge and contaminated soils using a soil-capping approach may be sufficient to minimize the possible adverse environmental impacts from the decommissioned waste pit, and this may represent an option that is superior to other costly remediation strategies.https://www.mdpi.com/2076-3417/12/3/1355oily sludgecontaminated soilsoilfieldpetroleum hydrocarbondesert
spellingShingle Hamad Al-Mebayedh
Anyi Niu
Chuxia Lin
Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
Applied Sciences
oily sludge
contaminated soils
oilfield
petroleum hydrocarbon
desert
title Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
title_full Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
title_fullStr Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
title_full_unstemmed Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
title_short Petroleum Hydrocarbon Composition of Oily Sludge and Contaminated Soils in a Decommissioned Oilfield Waste Pit under Desert Conditions
title_sort petroleum hydrocarbon composition of oily sludge and contaminated soils in a decommissioned oilfield waste pit under desert conditions
topic oily sludge
contaminated soils
oilfield
petroleum hydrocarbon
desert
url https://www.mdpi.com/2076-3417/12/3/1355
work_keys_str_mv AT hamadalmebayedh petroleumhydrocarboncompositionofoilysludgeandcontaminatedsoilsinadecommissionedoilfieldwastepitunderdesertconditions
AT anyiniu petroleumhydrocarboncompositionofoilysludgeandcontaminatedsoilsinadecommissionedoilfieldwastepitunderdesertconditions
AT chuxialin petroleumhydrocarboncompositionofoilysludgeandcontaminatedsoilsinadecommissionedoilfieldwastepitunderdesertconditions