The van der Waals idea of pseudo associations and the critical compressibility factor
The dimensionless value of critical compressibility factor in the van der Waals theory of gas-liquid critical point is a universal constant, Z_{c} = 0.375. Experimentally measured values of this quantity for simple fluids are considerably smaller than the theory prediction. Van der Waals once assume...
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| Format: | Article |
| Language: | English |
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Institute for Condensed Matter Physics
2020-03-01
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| Series: | Condensed Matter Physics |
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| Online Access: | https://doi.org/10.5488/CMP.23.13603 |